Microemulsion Seeded Polymerization of Styrene

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (7): 1166.

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Microemulsion Seeded Polymerization of Styrene

XU Xiang-Ling¹, ZHANG Zhi-Cheng¹, WU Xin¹, GE Xue-Wu¹, ZUO Ju², NIU Ai-Zhen²

1. Department of Applied Chemistry, University of Science and Technology of China, Hefei, 230026;
2. Department of Chemistry, State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation, Nankai University, Tianjin, 300071

Received:1997-05-20 Online:1998-07-24 Published:1998-07-24

Abstract

Abstract: Microemulsion seeded polymerizations of styrene were studied with γ ray or potassium persulfate. After examining the size of polymer particles and its distribution before and after polymerization, it was found that there were no new particles formed during polymerization, despite that there were micelles in aqueous phase. These micelles acted as monomer reservoir during polymerization, instead of nucleating loci. Due to the lower monomer content and the much more polymer particles in microemulsion seeded polymerization, its polymerization behavior was much different from the emulsion seeded polymerization.

Key words: Microemulsion polymerization, Seeded polymerization, Styrene

CLC Number:

O635

TrendMD:

XU Xiang-Ling, ZHANG Zhi-Cheng, WU Xin, GE Xue-Wu, ZUO Ju, NIU Ai-Zhen. Microemulsion Seeded Polymerization of Styrene[J]. Chem. J. Chinese Universities, 1998, 19(7): 1166.

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Microemulsion Seeded Polymerization of Styrene

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