Nonaqueous Synthesis and Crystal Structure of NH4ZnPO4

Abstract

Abstract: Single crystal of NH₄ZnPO₄ was synthesized from nonaqueous system and its crystal structure was determined using single crystal X-ray diffraction. The structure was solved by direct method and refined by full-matrix least-square method. The crystal is hexagonal with space group P6₃ and has a unit cell with a =1.0688(2) nm, c =0.8706(2) nm, V =0.8613(2) nm³, M_r=17838, μ =59.65 cm^-1, Z =8, D_c=2.751 g·cm^-3, R =0.035, R_w=0.078. There are no Zn_O_Zn and P_O_Plinkages in the structure. Both zinc and phosphorus atoms are four-coordinated to oxygen atoms. The framework structure contains six membered ring direct channels along c-axis. The linear Zn_O_Plinkage was first found in the structure of the phosphates.

Key words: Nonaqueous synthesis, Phosphate, Crystal structure

CLC Number:

O614.2

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XU Jia-Ning, YUAN Hong-Ming, SHI Su-Hua, SUN Jian-Min, SONG Tian-You, FENG Shou-Hua, XU Ru-Ren, Bu Wei-Ming, Mao You-Gang, Ye Ling, Fan YU-Guo . Nonaqueous Synthesis and Crystal Structure of NH₄ZnPO₄[J]. Chem. J. Chinese Universities, 1998, 19(11): 1707.

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Nonaqueous Synthesis and Crystal Structure of NH₄ZnPO₄

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