Synthesis of Copper(Ⅱ)Complex with meso-Tetra(4-hydroxyphenyl)Porphyrin by Solid State Reaction

Abstract

Abstract: The metalloporphyrin coordination complex(copper with meso-tetra(4-hydroxyphenyl) porphyrin)was synthesized by solid state reaction at room temperature.The molarratio of copper acetate(Cu(Ac)₂·H₂Oto T(4-HP)Pis 1:1.The reactants are mixed andgrinded in the agate mortar for 15 min.The reaction rate was detected by visible absorptionspectra.The soret band of ligand(422 nm)disappears,after the grinded sample is laid up for10 h at 12℃, and the soret band of complex appears at the 427 nm(the solvent is DMF).The reaction was finished within 1.5 h at 35℃, and was completed within 30 min at 35℃by initiation of ethanol(95%).The composition and conformation of products are characterized by elementary analysis,IR,fluorescence and DTA, Compared with the compound synthesized in liquid state in DMF,the composition and structure of the complex are the same.

Key words: Metalloporphyrin, Complex, Solid state reaction

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ZHANG Yin-Han, LIU Yun-Ping, NIO Qi-Dao, SONG Zi-Tai. Synthesis of Copper(Ⅱ)Complex with meso-Tetra(4-hydroxyphenyl)Porphyrin by Solid State Reaction[J]. Chem. J. Chinese Universities, 1996, 17(4): 526.

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Synthesis of Copper(Ⅱ)Complex with meso-Tetra(4-hydroxyphenyl)Porphyrin by Solid State Reaction

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