A Sensor Based on Chemiluminescence for the Determination of Mn2+

Abstract

Abstract: Achemiluminescence sensor for Mn²⁺combined with flow-injection system is presented in this paper. It was based on the new approach that all of the reagents involved in the chemiluminescence reaction were immobilized electrostatically on Amberlyst A-27 anion-ex-change resin. Mn²⁺can be sensed directly by the reaction with Luminol and IO₄^-, which were eluted by Na₃PO₄from the immobilization column prior to the chemiluminescence reaction. The linear range for Mn²⁺is 2. 0×10^-9-1.0×10^-5g/mL. The detection limit is 1.0×10^-9g/mL. The column with immobilized chemiluminescence reagents in the resin can be used for 100 times. The sensor has been applied to the determination of Mn²⁺in water samples.

Key words: Chemical sensor, Mn²⁺, Solid-state format, Chemiluminescence

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LU Jian-Zhong, ZHANG Zhu-Jun. A Sensor Based on Chemiluminescence for the Determination of Mn²⁺[J]. Chem. J. Chinese Universities, 1995, 16(7): 1034.

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A Sensor Based on Chemiluminescence for the Determination of Mn²⁺

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