Tunable Upconversion Luminescence of Mn2+ Doping NaBiF4∶Yb/Er Particles†

doi:10.7503/cjcu20170620

Abstract

Abstract:

NaBiF₄∶Yb/Er/Mn samples with different concentrations of Mn²⁺ were fabricated via the solvothermal method. Also, the morphology and crystal phase, the changes of upconversion luminescence(UCL) upon different doping amounts of Mn²⁺ were investigated. Meanwhile, the mechanism of energy transfer in NaBiF₄∶Yb/Er/Mn was also discussed. The results indicate that, for NaBiF₄∶Yb/Er, Mn²⁺ doping does not induce transition from hexagonal to cubic phase, but increases the size of the particles. Meanwhile, the energy transfer processes between Er³⁺ and Mn²⁺ can take place in NaBiF₄ host, which eventually enhances the red emission to a certain degree. With the increasing of the concentration of Mn²⁺, the intensity ratio of red to green emission is also increased. In addition, the temperature-dependent UCL spectra of NaBiF₄∶Yb/Er/Mn was investigated, and the intensity ratios of red to green emission and 520 nm green emission to 540 nm green emission are generally increased with elevated temperature.

Key words: NaBiF₄, Upconversion luminescence, Energy transfer, Temperature-dependent spectrum, Mn²⁺ doping

TrendMD:

SU Yue, LEI Pengpeng, FENG Jing, ZHANG Hongjie. Tunable Upconversion Luminescence of Mn²⁺ Doping NaBiF₄∶Yb/Er Particles^†[J]. Chem. J. Chinese Universities, 2017, 38(12): 2135.

Figures/Tables 9

Fig.1 XRD patterns of NaBiF4∶Yb/Er/Mn x(Mn): a. 0; b. 6%; c. 12%; d. 18%. (B) shows the magnified peaks located at 29.2° in (A).

Fig.2 XPS spectra of NaBiF4∶Yb/Er/Mn[x(Mn)=18%] (A) Bi4f72 and Bi4f52; (B) Na1s; (C) F1s; (D) Yb4d; (E) Er4d; (F) Mn2p32 and Mn2p12.

Fig.3 SEM images of NaBiF4∶Yb/Er/Mn x(Mn): (A) 0; (B) 6%; (C) 12%; (D) 18%.

Fig.4 TEM images of NaBiF4∶Yb/Er/Mn x(Mn): (A) 0; (B) 6%; (C) 12%; (D) 18%. The inset in (D) is the HRTEM image of NaBiF4∶Yb/Er/Mn.

Fig.5 UCL spectra of NaBiF4∶Yb/Er/Mn [x(Mn)=0, 6%, 12%, 18%] under 980 nm excitation(A), Rr/g(a) and calculated overall UCL intensity(b) with increasing Mn2+ concentration(B) and the CIE chromaticity diagram of NaBiF4∶Yb/Er/Mn[x(Mn)=0, 6%, 12%, 18%)](C) (A) The power density is 14.15 W/cm2.

Fig.5 lg-lg plot of the UCL intensities of NaBiF4∶Yb/Er/Mn[x(Mn)=18%] as a function of 980 nm pump power a. 2H11/2, 4S3/2→4I15/2, slope=2.14; b. 4F9/2→4I15/2, slope=2.39.

Fig.7 Energy level diagram and upconversion mechanism of NaBiF4∶Yb/Er/Mn under 980 nm excitation The full arrows pointing upwards represent energy absorption, full arrows pointing downwards represent visible emission, dashed arrows represent the nonradiative relaxation process, and the curly dashed arrows represent energy transfer.

Fig.8 UCL spectra of NaBiF4∶Yb/Er/Mn[x(Mn)=18%]recorded from 25 K to 500 K λex=980 nm, the power density is 7.08 W/cm2.

Fig.9 Temperature-dependent intensity of green emission a(2H11/2-4I15/2, a), green emission b(4S3/2-4I15/2, b)(A), temperature-dependent intensity of red emission(4F9/2 - 4I15/2)(B) and intensity ratio of red to green emission(a) and green emission a to green emission b(b) recorded from 25 K to 500 K(C)

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Tunable Upconversion Luminescence of Mn²⁺ Doping NaBiF₄∶Yb/Er Particles^†

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