Voltage Modulated Electrochemiluminescence for Highly Sensitive Detection

doi:10.7503/cjcu20200351

Abstract

Abstract:

A voltage modulated electrochemiluminescent（ECL） method is established for highly sensitive detection. In this new strategy， a small voltage is imposed at a constant voltage that could increase ECL intensity from luminol-hydrogen peroxide by ca. 2 times. This ECL intensity shows a good linear relationship with the concentration of hydrogen peroxide in the range of 1 nmol/L—200 μmol/L with a detection limit of 0.1 nmol/L（S/N=3）. The results exhibit that the voltage modulated ECL could be an effective way to increase ECL intensity， and more importantly， used to study the electrochemical process at the electrode interface.

Key words: Electrochemiluminescence, Voltage modulation, Luminol, Hydrogen peroxide, Highly sensitive detection

CLC Number:

O657

ZHANG Jingjing, JIN Rong, FANG Danjun, JIANG Dechen. Voltage Modulated Electrochemiluminescence for Highly Sensitive Detection[J]. Chemical Journal of Chinese Universities, 2020, 41(11): 2421-2425.

Figures/Tables 4

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Method	Potential/V	Liner range	Detection limit	Ref.
LSV?ECL^*	0—1.0	1.0—1000 nmol/L	0.456 nmol/L	[19]
Constant voltage?ECL	0.70	5.0—30 μmol/L		[20]
Cyclic voltammogram	0—1.0	5.0 μmol/L—1.0 mmol/L	5.0?μmol/L	[21]
Voltage modulate ECL	0.95—1.05	1.0 nmol/L—200 μmol/L	0.24 nmol/L	This work

Method	Potential/V	Liner range	Detection limit	Ref.
LSV?ECL^*	0—1.0	1.0—1000 nmol/L	0.456 nmol/L	[19]
Constant voltage?ECL	0.70	5.0—30 μmol/L		[20]
Cyclic voltammogram	0—1.0	5.0 μmol/L—1.0 mmol/L	5.0?μmol/L	[21]
Voltage modulate ECL	0.95—1.05	1.0 nmol/L—200 μmol/L	0.24 nmol/L	This work

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