A Chemiluminescent Zirconocene Coordination Tetrahedron

doi:10.7503/cjcu20210628

Abstract

Abstract:

Peroxyoxalate chemiluminescence（POCL） is widely employed in practical applications. In particular， a stable and highly efficient POCL system is a key factor in advanced emergency lights. To improve POCL efficiency， metal-organic cages（MOCs） are considered an excellent platform to employ. For this purpose， this study presents the first successful case of MOC in POCL system. A gigantic zirconocene tetrahedron（ZrT-6） was successfully synthesized， outperforming the used ligand in luminescent intensity and lifetime. This cage can also maintain good stability during the POCL test.

Key words: Chemiluminescent, Zirconocene tetrahedron, Peroxyoxalate chemiluminescence, Self-assembly

CLC Number:

O641

TrendMD:

DU Shunfu, WANG Wenjing, EL⁃SAYED El⁃Sayed M., SU Kongzhao, YUAN Daqiang, HONG Maochun. A Chemiluminescent Zirconocene Coordination Tetrahedron[J]. Chem. J. Chinese Universities, 2022, 43(1): 20210628.

Figures/Tables 3

References 28

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