Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (6): 952.

• Articles • Previous Articles     Next Articles

Establishment of New Research System to Combine Electrochemistry and Electron Spectroscopy and the Investigations of Surface Chemical States of Pt/BiadElectrode

SUN Shi-Gang1, CHEN Sheng-pei1, CHEN Bao-Zhu2, XU Fu-Chun3, XUE Guo-Qing1, LIN Wen-Feng1, GE Fu-Yun3   

  1. 1. State Key Laboratry for Phys.Chem.of the Solid Surface, Dept.of Chem.Institute of Phys.Chem., Xiamen University, Xiamen, 361005;
    2. Dept.of Sci.Instruments, Xiamen University, Xiamen, 361005;
    3. Analytical Centre, Xiamen University, Xiamen, 361005
  • Received:1994-10-25 Revised:1995-04-14 Online:1995-06-24 Published:1995-06-24

Abstract: A new research system,which allows samples to be transferred rapidly and without contamination between electrochemical environment and ultra-hight-vacuum chamber,has been set up recently. This system is of interest to combine investigations on structure and proporties of solid surface at both solid/liquid and solid/gas interfaces.The prelimiary study of Pt/Biadelectrode at levels of chemical environment and electronic structure demonstrated the success of the system established.The XPS data indicate that two oxidation states of Bi adatom existe on Pt/Biadelectrode surface.The present results give new interpretation of the promoting mechanism of Bi adatom in electrocatalysis.

Key words: Electrochemistry, Electron spectroscopy, Pt/Biadelectrode, Surface chemical states

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