Synthesis of Ru3(CO)12 Cluster in Zeolite NaY Using Ship-in-Bottle Technique

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (3): 336.

• Articles • Previous Articles Next Articles

Synthesis of Ru₃(CO)₁₂ Cluster in Zeolite NaY Using Ship-in-Bottle Technique

XIAO Feng-Shou, XU Ru-Ren, HE Ya-Nan, DING Hong, ZHANG Yan-Qiu

Department of Chemistry, Jilin University, Changchun, 130023

Received:1993-06-19 Revised:1993-08-14 Online:1994-03-24 Published:1994-03-24

Abstract

Abstract: NaYzeolite entrapped Ru₃(CO)₁₂ cluster has been synthesized from RuCl₃ ion-exchanged NaY, which is well charactrized by IRand Raman spectroscopies and COchemisorption.The in situ IRspectrum exhibits the bands at 2060, 2040, 2017, 1990, and 1953 cm^-1, which are closed to Ru₃(CO)₁₂ crystalline.Furthermore, the Raman results provide the bands at 150 and 185 cm^-1, which are attributed to Ru-Ru bonds of the triruthenium carbonyl cluster.COchemisorption on Ru₃/NaY gives a CO/Ru ratio of 3.85,which is similar to the stochiometry of Ru₃(CO)₁₂.

Key words: Cluster, Ru₃(CO)₁₂, NaY zeolite, Ruthenium, Carbonyl

TrendMD:

XIAO Feng-Shou, XU Ru-Ren, HE Ya-Nan, DING Hong, ZHANG Yan-Qiu. Synthesis of Ru₃(CO)₁₂ Cluster in Zeolite NaY Using Ship-in-Bottle Technique[J]. Chem. J. Chinese Universities, 1994, 15(3): 336.

[1]	LIN Zhi, PENG Zhiming, HE Weiqing, SHEN Shaohua. Single-atom and Cluster Photocatalysis： Competition and Cooperation [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220312.
[2]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[3]	WANG Junyang, LIU Zheng, ZHANG Qian, SUN Chunyan, LI Hongxia. Application of DNA Silver Nanoclusters in the Fluorescence Biosensors based on Functional Nucleic Acids [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220010.
[4]	XU Siran, YIN Hengbo, XUE Dongping, XIA Huicong, ZHAO Shuyan, YAN Wenfu, MU Shichun, ZHANG Jianan. Atomically Dispersed Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction Reaction [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220028.
[5]	ZHANG Liling, LIU Liu, ZHENG Mingqiu, FANG Wenkai, LIU Da, TANG Hongwu. Dual Signal Detection of HPV16 DNA by CRISPR/Cas12a Biosensing System Based on Upconversion Luminescent Resonance Energy Transfer [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220412.
[6]	WANG Yuanyue, AN Suosuo, ZHENG Xuming, ZHAO Yanying. Spectroscopic and Theoretical Studies on 5-Mercapto-1，3，4-thiadiazole-2-thione Microsolvation Clusters [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220354.
[7]	CHEN Chongan, YANG Guoyu. Two B₅O_n（n=11， 12） Cluster-based Borates with Deep UV Cutoff Edge [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210711.
[8]	TAN Yuling, YANG Ling, YU Hong, NI Chunyan, LANG Jianping. Progress of the Synthesis of High-Nuclearity Ag/S Nanoclusters [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210476.
[9]	DU Jiahui, LIAO Kang, HONG Benkun, WANG Zhongye, MA Jing, LI Wei, LI Shuhua. Generalized Energy-based Fragmentation Clustering Algorithm for Localized Excited States [J]. Chem. J. Chinese Universities, 2021, 42(7): 2227.
[10]	REN Ying, LI Changhua, WANG Tao, XUE Shanshan, ZHANG Tingting, JIA Jianfeng, WU Haishun. Theoretical Studies on Pd-catalyzed Oxidative N─H Carbonylation to Synthesis of 1，3，4-Oxadiazole-2（3H）-one Heterocyclic Compounds [J]. Chem. J. Chinese Universities, 2021, 42(6): 1793.
[11]	DUAN Jun, ZHOU Pingping, ZHANG Liqian, MA Lin, YU Wen, ZHU Meiqi, ZHUANG Minyan, YANG Fenglei, CAO Changsheng, ZHANG Peng, SHI Yanhui. Syntheses of Imidazole-coordinated Ru（II） Half-sandwich Macrocyclic Complexes and Their Anti-cancer Activity [J]. Chem. J. Chinese Universities, 2021, 42(12): 3589.
[12]	YANG Xinjie, LAI Yanqiong, LI Qiuyang, ZHANG Yanli, WANG Hongbin, PANG Pengfei, YANG Wenrong. An Enzyme-free and Label-free Fluorescent Probe for Detection of Microcystin-LR Based on Circular DNA-Silver Nanoclusters [J]. Chem. J. Chinese Universities, 2021, 42(12): 3600.
[13]	WANG Bodong, PAN Meichen, ZHUO Ying. Construction of Electrochemiluminescence Sensing Interface Based on Silver Nanoclusters-Silica Nanoparticles and Biomolecular Recognition [J]. Chem. J. Chinese Universities, 2021, 42(11): 3519.
[14]	WANG Peng, LIU Huan, YANG Da. Recent Advances on Hydrocarbonylation of Unsaturated Hydrocarbons by Involving Carbon Monoxide [J]. Chem. J. Chinese Universities, 2021, 42(10): 3024.
[15]	HUANG Yunshuai, YANG Ni, WU Zehong, WU Si. Ruthenium Complexes with Photoresponsive Coordination Bonds for Light-controlled Surface Functions ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1174.

Synthesis of Ru₃(CO)₁₂ Cluster in Zeolite NaY Using Ship-in-Bottle Technique

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments