Ionic Conduction of Polymer Electrolytes Based on an Alternating Maleic Anhydride Copolymer with Oligo-oxyethylene Side Chains

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (11): 1727.

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Ionic Conduction of Polymer Electrolytes Based on an Alternating Maleic Anhydride Copolymer with Oligo-oxyethylene Side Chains

DING Li-Ming, LIN Yun-Qing, ZNOU Zi-Nan, WANG Fo-Song

Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022

Received:1993-11-03 Revised:1994-03-29 Online:1994-11-24 Published:1994-11-24

Abstract

Abstract: In this paper, the ionic conductivity of the BM350-LiClO₄ complexes was studied as a function of temperature and salt concentration.At high salt concentrations, the more pronounced fall in conductivity in the solid medium has been interpreted as being due to the effect of T_g and bulk viscosity on ion transport. Conductivities which displayed non-Arrhe-nius behviour were analysed using the Vogel-Tammann-Fulcher equation and interpreted on the basis of the configurational entropy model derived by Gibbs and coworkers.

Key words: Solid polymer electrolytes, Ionic conductivity, Glass transition temperature, Ion transport, VTF equation

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DING Li-Ming, LIN Yun-Qing, ZNOU Zi-Nan, WANG Fo-Song. Ionic Conduction of Polymer Electrolytes Based on an Alternating Maleic Anhydride Copolymer with Oligo-oxyethylene Side Chains[J]. Chem. J. Chinese Universities, 1994, 15(11): 1727.

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Ionic Conduction of Polymer Electrolytes Based on an Alternating Maleic Anhydride Copolymer with Oligo-oxyethylene Side Chains

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