Studies on the Solid State Reactions of Coordination Compounds(LXVII)─The Synthesis of Mixed Ligand Complexes in Solid State

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (10): 1443.

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Studies on the Solid State Reactions of Coordination Compounds(LXVII)─The Synthesis of Mixed Ligand Complexes in Solid State

ZHANG Wei-Ling, ZHENG Li-Min, LEI Li-Xu, XIN Xin-Quan

Department of Chemistry, Coodination Chemistry State Key Laboratory, Nanjing University, Nanjing 210008

Received:1994-02-18 Revised:1994-05-11 Online:1994-10-24 Published:1994-10-24

Abstract

Abstract: The solid state reactions of diaqua bis(acetylacetonate)cobalt(II)[Co(acac)₂(H₂O)₂]with organic ligands:2, 2'-bipyridyl, 1, 10-phenanthroline, 8-quinolinol and salicylaloxime have been investigated at room or near room temperature. The mixed ligand complexes:Co(acac)₂(bipy), Co(acac)₂(1, 10-phen), Co(acac)₂(8-HQ)₂·2H₂O, Co(acac)·(SAO)(H₂O)have been characterized by the results of UV, FTIR, XRDand elementary analyses.

Key words: Mixed ligand complex, Solid state reaction at room temperature, Diaqua bis(acetylacetonate)cobalt(II), 8-Hydroxyquinoline, 2, 2'-bipyridyl

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ZHANG Wei-Ling, ZHENG Li-Min, LEI Li-Xu, XIN Xin-Quan. Studies on the Solid State Reactions of Coordination Compounds(LXVII)─The Synthesis of Mixed Ligand Complexes in Solid State[J]. Chem. J. Chinese Universities, 1994, 15(10): 1443.

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Studies on the Solid State Reactions of Coordination Compounds(LXVII)─The Synthesis of Mixed Ligand Complexes in Solid State

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