Studies on Catalysis of μ-Oxo-bisporphinatomanganese ( Ⅲ ) for Cyclohexane Monooxygenation

Abstract

Abstract: This paper first reported the catalysis for cyclohexane monooxygenation with PhIOat room temperature and in air atmosphere by μ-oxo-bisporphinatomanganese ( Ⅲ ) compounds.Compared with other metalloporphyrins reported so far, μ-oxo-bisporphinatomanganese ( Ⅲ) showed the better catalytic properties on cyclohexane hydroxylation.The kinetic researches found that there existed Hammett relationship between the substituents on porphyrin rings and the rate constants of the reactions catalyzed by μ-oxo-bisporphinatomanganese (Ⅲ).

Key words: [TXPPMn^Ⅲ]₂O, Monooxygenation, Kinetics

TrendMD:

GUO Can-Cheng, LIU Lian-Ying. Studies on Catalysis of μ-Oxo-bisporphinatomanganese ( Ⅲ ) for Cyclohexane Monooxygenation[J]. Chem. J. Chinese Universities, 1993, 14(8): 1083.

[1]	SUN Cuihong, LYU Liqiang, LIU Ying, WANG Yan, YANG Jing, ZHANG Shaowen. Mechanism and Kinetics on the Reaction of Isopropyl Nitrate with Cl， OH and NO₃ Radicals [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210591.
[2]	FAN Xiaoyong, WU Yan, SUN Ruibo, GOU Lei, LI Donglin. Construction and Zn Storage Performance of Three Dimensional Porous MnO_x@In₂O₃ Cubes [J]. Chem. J. Chinese Universities, 2021, 42(6): 1816.
[3]	WANG Renheng, XIAO Zhe, LI Yan, SUN Yiling, FAN Shuting, ZHENG Junchao, QIAN Zhengfang, HE Zhenjiang. Synthesis of Li₂FeP₂O₇ Cathode Material at Different Temperatures and Its Electrochemical Performance for Lithium Ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(4): 1299.
[4]	MA Zihui, WANG Mengyan, CAO Hongyu, TANG Qian, WANG Lihao, ZHENG Xuefang. Transient Absorption and Decay Kinetic Properties of Photo-excited Metal Coordinated Tetraphenylporphyrin [J]. Chem. J. Chinese Universities, 2021, 42(3): 767.
[5]	SHUAI Die, ZHAO Meijuan, CHEN Bingnian, WANG Li. Inhibitory Effect of Four Kinds of Keegin-type Phosphomolybdate on Tyrosinase and Melanin Formation and Its Antioxidant Activities [J]. Chem. J. Chinese Universities, 2021, 42(12): 3579.
[6]	ZHANG Aiqin, WANG Man, SHEN Gangyi, JIN Jun. Interactions Between Polybrominated Diphenyl Ethers and Human Serum Albumin Using SPR and Molecular Docking [J]. Chem. J. Chinese Universities, 2020, 41(9): 2054.
[7]	NING Qiuyang, LI Wancheng. Preparation of Planar C₂H₅OH Fast Response Gas Sensor [J]. Chem. J. Chinese Universities, 2020, 41(8): 1745.
[8]	NING Qiuyang, FENG Wei, WU Guoguang. Preparation of InN-In₂O₃ Nanocomposite with Bottle-shaped Structure and Its Enhanced Formaldehyde Gas Sensitivity [J]. Chem. J. Chinese Universities, 2020, 41(12): 2804.
[9]	WANG Lianping,LI Qingjie,LIU Xiaoyan,REN Yueying,YANG Xiuwei. Screening of Cholinesterase Inhibitors in Fructus Evodiae Alkaloids Based on UFLC-MS/molecular Simulation ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 111.
[10]	ABUDUHEIREMU Awati,ZHANG Dedong,HALIDAN Maimaiti. Preparation and CO₂ Reduction Performance of Composite Photocatalyst Based on Aminated Coal-based Carbon Dots^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 306.
[11]	WANG Zhipeng,NIU Zhuzhu,BAN Lijun,HAO Quanai,ZHANG Hongxi,LI Haitao,ZHAO Yongxiang. Formaldehyde Ethynylation Reaction over Cu₂O Supported on TiO₂ with Different Phases^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 334.
[12]	Yuzhen DUAN,Jinyu ZHU,Junming GUO,Mingwu XIANG,Xiaofang LIU,Hongli BAI,Changwei SU. Synthesis and Electrochemical Properties of Spinel Lithium Manganese Cathode Material LiNi_0.01Co_0.03Mn_1.96O₄ ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2574.
[13]	SUN Guangdong, PAN Xiaopeng, ZHONG Yuhao, CHEN Enyu, HUANG Yi, SHAO Jianzhong. Photopolymerization Kinetics of Poly(Acrylate Acid) Hydrogels Induced by Blue Light ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2404.
[14]	XIAO Biyuan,QIU Jiangyuan,QIN Fanghong,WAN Ting,XU Yaqun,NONG Xiaohui,HUANG Zaiyin. Study on Particle Size Effect on Adsorption Thermodynamics and Kinetics of Cubic Nano-Cu₂O ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2214.
[15]	SHI Weiguang,QING Hongxia,ZHANG Shangshang,LU Xiaoyi,WANG Xiaofeng,LI Benxian,XU Xiaohu,LIU Weiguo,WANG Jun,DONG Zhaohui. Kinetics and Abnormal Inhibition of THF on Ethylene Hydrate Formation from Ice Powder Based on Conversion Rate^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1968.

Studies on Catalysis of μ-Oxo-bisporphinatomanganese ( Ⅲ ) for Cyclohexane Monooxygenation

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments