Synthesis of Cobalt Porphyrin Containing Aliphatic Chains, and Its LB Films and Gas Sensitivity

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (2): 147.

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Synthesis of Cobalt Porphyrin Containing Aliphatic Chains, and Its LB Films and Gas Sensitivity

WEN Ke¹, LI Cao-Hui¹, CAO Xi-Zhang¹, GU Chang-Zhi², ZHANG Tong², SUN Liang-Yan²

1. Deft, of Chem., Jilin Univ., Changchun, 130023;
2. Dept.of Electronic Science, Jilin Univ.

Received:1992-04-06 Revised:1992-08-22 Online:1993-02-24 Published:1993-02-24

Abstract

Abstract: Tetra-(4-N,N-dimethylaminophenyl)porphyrin(TDMAPP) reacts with n-C₁₆H₃₃Br to yield the product tetra(4-N,N,N-dimethyl hexadecylaminophenyl)porphyrin bromide (TDMHAPPBr).Its cobalt complex was also prepared.Both porphyrin and its complex have good film-forming properties.The UV-visible spectra of the LBfilms and solid state show that the two states have different styles in the molecular interactions.The gas sensitivity study of the cobalt complex indicates that the complex is sensitive to NH₃ and has a good selectivity.The response and recovery times are short.

Key words: Porphyrin, LB films, Gas sensitivity

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WEN Ke, LI Cao-Hui, CAO Xi-Zhang, GU Chang-Zhi, ZHANG Tong, SUN Liang-Yan . Synthesis of Cobalt Porphyrin Containing Aliphatic Chains, and Its LB Films and Gas Sensitivity[J]. Chem. J. Chinese Universities, 1993, 14(2): 147.

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Synthesis of Cobalt Porphyrin Containing Aliphatic Chains, and Its LB Films and Gas Sensitivity

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