Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (9): 957.

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Hydrogen Diffusion in Amorphous MmNi4.5 Mn0.5 Film

Chao Jinlan, Zhou Zuoxiang, Wang Chunming, Jia Yuqun, He Lanling   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1987-03-24 Online:1988-09-24 Published:1988-09-24

Abstract: The MmNi4.5Mn0.5 (Mm. misch rare earth elements) thin film was prepared by conventional vacuum deposition technique. MmNi4.5Mn0.5 powder was placed on tantalum boat which was preheated at a temperature of;1400℃.All the component of MmNi4.5Mn0.5 evaporated immediately at this temperature and was deposited onto a cleaned palladium film (0.040mm) which was-placed just: above the tantalum boat. Analysis of the film was performed by means of X-ray fluorescence spectroscopy and it was confirmed that the composition was MmNi4.5Mn0.5. It was shown by X-ray diffraction spectroscopy that the MmNi4.5 Mn0.5 film was amorph-cus alloys.The diffusion coefficient of hydrogen in the film at ambient temperature has been studied with electrpchmical technique. The diffusion coefficient Dof hydrogen in amorphous MmNi4.5Mn0.5 alloy film was determined, the value of Dis (2.46±0.36)×10-7cm2/s.

Key words: Hydrogen, Diffusion, Fifm

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