Self-assembly of PNDC-b-PTPE to Prepare Thin Films with Both Structure and Luminescent Color

doi:10.7503/cjcu20230291

Abstract

Abstract:

Big steric monomer with aggregation induced emission tetraphenylethylene group， norbornenyl modified with tetraphenyl ethylene（NTPE）， was designed and synthesized， dendronized block copolymer poly（decanephenyl terephthalate based norbornene）-block-poly（norbornenyl modified with tetraphenyl ethylene）（PNDC-b-PNTPE） was prepared by sequential ring-opening metathesis polymerization（ROMP） of NTPE and dendronized monomer with di-decanyl groups， decanephenyl terephthalate based norbornene（NDC）. One-dimensional photonic crystal（1D PC） thin film with both structural color and luminescent emission was prepared by thin film self-assembly. The experimental results showed that the 1D PC thin film， which reflects blue color， was prepared by quick self-assembly of PNDC-b-PNTPE in tetrahydrofuran（THF）， the maximum reflection wavelength（λ_max） was 443 nm. Scanning electron microscopy image of the cross section of the 1D PC thin film showed that the PNDC-b-PNTPE self-assembled into lamellar structures with periodicity of 133 nm. Fluorescent emission spectrum showed that the luminescent emission of the self-assembled 1D PC thin film was 425 nm. The 1D PC thin film with both structural color and luminescent emission shows potential in display and anti-counterfeiting fields.

Key words: Block copolymer, Self-assembly, One-dimensional photonic crystal, Aggregation induced emission

CLC Number:

O632.13

TrendMD:

DUAN Xiaoli, HAN Huimin, ZHAO Mingkun, REN Lixia. Self-assembly of PNDC-b-PTPE to Prepare Thin Films with Both Structure and Luminescent Color[J]. Chem. J. Chinese Universities, 2023, 44(11): 20230291.

Figures/Tables 4

References 21

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