Chem. J. Chinese Universities ›› 2020, Vol. 41 ›› Issue (4): 765.doi: 10.7503/cjcu20190573
• Physical Chemistry • Previous Articles Next Articles
MENG Fanxing1,YU Zhiquan1,JING Wenwen1,WANG Yao1,2,SUN Zhichao1,WANG Anjie1,2,*()
Received:
2019-11-05
Online:
2020-04-10
Published:
2020-02-21
Contact:
Anjie WANG
E-mail:ajwang@dlut.edu.cn
Supported by:
CLC Number:
TrendMD:
MENG Fanxing, YU Zhiquan, JING Wenwen, WANG Yao, SUN Zhichao, WANG Anjie. Promoting Effect of Cerous Phosphate on the Phenol Catalytic Transfer Hydrogenation over Nickel Phosphide Catalyst †[J]. Chem. J. Chinese Universities, 2020, 41(4): 765.
Catalyst | Crystallite sizea/nm | Particle sizeb/nm | Relative acid amountc |
---|---|---|---|
Ni3P | 68.2 | 84.5 | 1 |
CePO4(0.05)-Ni3P | 29.3 | 29.3 | 10.6 |
CePO4(0.1)-Ni3P | 27.5 | 27.7 | 16.6 |
CePO4(0.2)-Ni3P | 26.9 | 24.3 | 17.6 |
CePO4(0.3)-Ni3P | 10.4 | 21.2 | 19.4 |
Catalyst | Crystallite sizea/nm | Particle sizeb/nm | Relative acid amountc |
---|---|---|---|
Ni3P | 68.2 | 84.5 | 1 |
CePO4(0.05)-Ni3P | 29.3 | 29.3 | 10.6 |
CePO4(0.1)-Ni3P | 27.5 | 27.7 | 16.6 |
CePO4(0.2)-Ni3P | 26.9 | 24.3 | 17.6 |
CePO4(0.3)-Ni3P | 10.4 | 21.2 | 19.4 |
Catalyst | Conversion(%) | Selectivity(%) | |
---|---|---|---|
Cyclohexanone | Cyclohexanol | ||
Ni3P | 68.8 | 7.1 | 92.9 |
CePO4(0.05)-Ni3P | 83.1 | 7.6 | 92.4 |
CePO4(0.1)-Ni3P | 85.1 | 8.0 | 92.0 |
CePO4(0.2)-Ni3P | 87.7 | 8.0 | 92.0 |
CePO4(0.3)-Ni3P | 83.3 | 10.3 | 89.7 |
Catalyst | Conversion(%) | Selectivity(%) | |
---|---|---|---|
Cyclohexanone | Cyclohexanol | ||
Ni3P | 68.8 | 7.1 | 92.9 |
CePO4(0.05)-Ni3P | 83.1 | 7.6 | 92.4 |
CePO4(0.1)-Ni3P | 85.1 | 8.0 | 92.0 |
CePO4(0.2)-Ni3P | 87.7 | 8.0 | 92.0 |
CePO4(0.3)-Ni3P | 83.3 | 10.3 | 89.7 |
Hydrogen donor | Conversion(%) | Selectivity(%) | |
---|---|---|---|
Cyclohexanone | Cyclohexanol | ||
Methanol | 2.0 | 49.5 | 50.5 |
Ethanol | 5.9 | 27.0 | 73.0 |
n-Propanol | 18.4 | 18.8 | 81.2 |
2-Propanol | 87.7 | 8.0 | 92.0 |
2-Butanol | 72.3 | 11.6 | 88.4 |
1,2-Propanediol | 25.2 | 34.1 | 65.9 |
Glycerol | 1.3 | 48.9 | 51.1 |
Hydrogen donor | Conversion(%) | Selectivity(%) | |
---|---|---|---|
Cyclohexanone | Cyclohexanol | ||
Methanol | 2.0 | 49.5 | 50.5 |
Ethanol | 5.9 | 27.0 | 73.0 |
n-Propanol | 18.4 | 18.8 | 81.2 |
2-Propanol | 87.7 | 8.0 | 92.0 |
2-Butanol | 72.3 | 11.6 | 88.4 |
1,2-Propanediol | 25.2 | 34.1 | 65.9 |
Glycerol | 1.3 | 48.9 | 51.1 |
Catalyst | Temperature/℃ | 103Rate constant/ min-1 | Ea/ (kJ·mol-1) |
---|---|---|---|
CePO4(0.2)-Ni3P | 180 | 4.16 | 27.9 |
200 | 5.74 | ||
220 | 7.56 | ||
Ni3P | 180 | 1.64 | 62.3 |
200 | 3.25 | ||
220 | 6.28 |
Catalyst | Temperature/℃ | 103Rate constant/ min-1 | Ea/ (kJ·mol-1) |
---|---|---|---|
CePO4(0.2)-Ni3P | 180 | 4.16 | 27.9 |
200 | 5.74 | ||
220 | 7.56 | ||
Ni3P | 180 | 1.64 | 62.3 |
200 | 3.25 | ||
220 | 6.28 |
[1] | Chen C ., Zn-based Catalysts for Hydrodeoxygenation of Phenolics from Biomass Oils, Zhejiang University, Hangzhou, 2019 |
( 陈辰 . 基于生物质油中酚类化合物加氢脱氧的Zn基催化剂研究, 杭州: 浙江大学, 2019) | |
[2] | Zhang Q. S., Li H. F., Gao P., Chin. J. Catal., 2014, 35, 1793— 1799 |
[3] | Ding S., Zhang C., Liu Y., Appl. Surf. Sci., 2017, 425, 484— 491 |
[4] | Li A., Shen K., Chen J., Chem. Eng. Sci., 2017, 166, 66— 76 |
[5] | Xiang Y. Z., Ma L., Lu C. S., Zhang Q. F., Li X. N., Green Chem., 2008, 10, 939— 943 |
[6] | Shore S. G., Ding E., Park C., Keane M. A., Catal. Commun., 2002, 3, 77— 84 |
[7] | Shafaghat H., Lee I. G., Jae J., Chem. Eng. J., 2019, 377, 119986— 119993 |
[8] | Gilkey M. J., Xu B. J., ACS Catal., 2016, 6, 1420— 1436 |
[9] | Robertson A., Matsumoto T., Ogo S., Dalton Trans., 2011, 40, 10304— 10310 |
[10] | Vilches-Herrera M., Werkmeister S., Junge K., Catal. Sci. Technol., 2014, 4, 629— 632 |
[11] | Liu R., Wang Y., Cheng H., Yu Y., Zhao F., Arai M ., J. Mol. Catal. A: Chem., 2013, 366, 315— 320 |
[12] | Elie M. R., Clausen C. A., Geiger C. L., J. Hazard. Mater., 2012, 203/204, 77— 85 |
[13] | Radhakrishan R., Do D. M., Jaenicke S., Sasson Y., ACS Catal., 2011, 1, 1631— 1636 |
[14] | Xiang Y., Li X., Lu C., Ma L., Zhang Q., Appl. Catal. A, 2010, 375, 289— 294 |
[15] | Farhadi S., Kazem M., Siadatnasab F ., Polyhedron., 2011, 30, 606— 613 |
[16] | Shafaghat H., Rezaei P. S ., J. Taiwan Inst. Chem. Eng., 2016, 65, 91— 100 |
[17] | Zhang J., Dong K., Luo W., Guan H., ACS Omega, 2018, 3, 6206— 6216 |
[18] | Song J., Zhou B., Zhou H., Wu L., Meng Q., Liu Z., Han B., Angew. Chem. Int. Ed., 2015, 54, 9399— 9403 |
[19] | Wojciechowska J., Jędrzejczyk M., Grams J., Keller N., Ruppert A. M ., ChemSusChem, 2019, 12, 639— 650 |
[20] | Wang J., Nie R., Xu L., Lyu X., Lu X., Green Chem., 2019, 21, 314— 320 |
[21] | Cohen R. C., Graves R., Nguyen S. T., Martin J. M. L., J. Am. Chem. Soc., 2004, 126, 14796— 14803 |
[22] | Tang Z. C., Cao H. T., Tao Y. H., Heeresa H. J., Pescarmona P. P., Appl. Catal. B, 2020, 263, 118273— 118283 |
[23] | Yu Z. Q., Wang Y., Liu S., Yao Y. L., Sun Z. C., Li X., Liu Y. Y., Wang W., Wang A. J., Camaioni D. M., Lercher J. A., Ind. Eng. Chem. Res., 2018, 57, 10216— 10225 |
[24] | Wang F. M., Chen J. W., Qi X. P., Yang H., Jiang H. H., Deng Y. Q., Liang T. X., Appl. Surf. Sci., 2019, 481, 1403— 1411 |
[25] | Zeng Y. Q., Wang Y. A., Zhang S. L., Zhong Q., Rong W. L., Li X. H., J. Colloid Interface Sci., 2018, 524, 8— 15 |
[26] | Cecilia J. A., Infantes-Molina A., Rodríguez-Castellón E., Jiménez-López A., Oyama S. T., Appl. Catal. B, 2013, 136/137, 140— 149 |
[27] | Li D., Bui P., Zhao H. Y., Oyama S. T., Dou T., Shen Z. H., J. Catal., 2012, 290, 1— 12 |
[28] | Sisira S., Jacob L. A., Mani K. P., Biju P. R., Unnikrishnan N. V., Joseph C ., J. Mater. Sci. : Mater. Electron., 2019, 30, 11354— 11367 |
[29] | Beche E., Charvin P., Perarnau D., Abanades S., Flamant G., Surf. Interface Anal., 2008, 40, 264— 267 |
[30] | Reddy B. M., Khan A., Yamada Y., Kobayashi T., Loridant S., Volta J. C., J. Phys. Chem. B, 2003, 107, 5162-5167 |
[31] | Zhang C. T., Huo Z. B., Ren D. Z., J. Energy Chem., 2018, 32, 1— 9 |
[32] | Kuwahara Y., Kaburagi W., Osada Y., Catal. Today, 2017, 281, 418— 428 |
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