High-performance Adhesive Material at Dry and Under-seawater Conditions Based on Catechol-functionalized Alternating Copolymer†

doi:10.7503/cjcu20200060

Abstract

Abstract:

A novel catechol-functionalized alternating copolymer, poly(dopamine-alt-bisphenol A epoxy resin)[P(DA-a-BAER)], was synthesized from the copolymerization between dopamine(DA) and bisphenol A epoxy resin(BAER) monomers via an epoxy-amino click reaction. The resultant alternating copolymer was used as an adhesive material, of which the bonding performances both at dry and under-seawater conditions were investigated with the usage of FeCl₃ as cross-linker. The results showed that P(DA-a-BAER) could achieve excellent bonding strength on various substrates both at dry and under-seawater conditions. Taking stainless steel as an example, a bonding strength of (3.03±0.68) MPa was achieved at atmospheric situation with a 1:3 molar ratio of Fe³⁺ to catechol groups; an under-seawater bonding strength of (0.65±0.10) MPa was achieved when the molar ratio of Fe³⁺ to catechol groups reached 1:6. The crosslinking mechanism of Fe³⁺ was studied by Raman spectrometry and UV-Vis absorption spectrometry, demonstrating that catechol moieties underwent oxidation crosslinking and coordination crosslinking processes. As a result, the cohesion strength of the polymer was enhanced, leading to a high bonding strength.

Key words: Mussel, Bioadhesive, Catechol, Bisphenol A

CLC Number:

O633.4

TrendMD:

SHA Xinyi, ZHANG Changxu, WANG Yuling, ZHOU Yongfeng. High-performance Adhesive Material at Dry and Under-seawater Conditions Based on Catechol-functionalized Alternating Copolymer^†[J]. Chem. J. Chinese Universities, 2020, 41(7): 1477.

Figures/Tables 7

References 29

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Dry-state adhesion strength/MPa	Ref.	Underwater adhesion strength/MPa	Ref.
3.03	This work	0.65	This work
ca.3	[13]	ca.0.4	[16]
ca.2	[22]	0.2	[24]
4.0	[24]	1.33	[26]
0.73	[26]	1.13	[28]
5.7	[27]	0.65	[29]

Dry-state adhesion strength/MPa	Ref.	Underwater adhesion strength/MPa	Ref.
3.03	This work	0.65	This work
ca.3	[13]	ca.0.4	[16]
ca.2	[22]	0.2	[24]
4.0	[24]	1.33	[26]
0.73	[26]	1.13	[28]
5.7	[27]	0.65	[29]