Preparation of NiO Doped Beta-Al2O3 Solid Electrolyte via a Low Temperature Combustion Method†

doi:10.7503/cjcu20160143

Abstract

Abstract:

NiO doped and Li₂O stabilized Beta-Al₂O₃ solid electrolyte was synthesized via a citrate sol-gel low temperature combustion method. Effects of the NiO content on the mechanical and electrical performances were studied by means of thermogravimetry/differential scanning calorimetry(TG/DSC), X-ray diffraction(XRD) and scanning electron microscopy(SEM). Meanwhile, the relative density, the bending strength and the electrical properties of the prepared samples were also measured. When the content(mass fraction) of NiO in Beta-Al₂O₃ solid electrolyte is 0.10%, the content of β″-Al₂O₃ phase is 88.33%, the microstructure is uniform and compact, the relative density is 99.75%, the bending strength is up to 248 MPa and the ionic conductivity can reach 0.108 S/cm at 350 ℃.

Key words: Beta-Al2O3 solid electrolyte, Sol-gel low temperature combustion method, NiO doping, Bending strength

CLC Number:

O614.8
O646

TrendMD:

HONG Yongfei, ZHU Chengfei, HUANG Pan, JI Guanghui. Preparation of NiO Doped Beta-Al₂O₃ Solid Electrolyte via a Low Temperature Combustion Method^†[J]. Chem. J. Chinese Universities, 2016, 37(6): 1030.

Figures/Tables 10

Fig.1 XRD patterns of the dry gel without(a) or with 0.15% NiO(b)

Fig.2 TG/DSC curves of the dry gel without(A) and with 0.15% NiO(B)

Fig.3 XRD patterns of precursor calcined at different temperaturesCalcination temperature/℃: a. 900; b. 950; c. 1000; d. 1050; e. 1100; f. 1150.

Fig.4 XRD patterns of the sintered samples with various amounts of NiOw(NiO)(%): a. 0; b. 0.05; c. 0.1; d. 0.15; e. 0.2; f. 0.25.

Fig.5 Cross section micrograph of the sintered samples with various amounts of NiOw(NiO)(%): (A) 0; (B) 0.05; (C) 0.1; (D) 0.15; (E) 0.2; (F) 0.25.

Fig.6 Density and relative density of the sintered samples with various amounts of NiO

Fig.7 Bending strength of the sintered samples with various amounts of NiO

Fig.8 Arrhenius plot of the sintered samples with various amounts of NiO

Fig.9 Impendence spectra of the sintered samples with various amounts of NiO at 350 ℃

Fig.10 Ionic conductivity of the sintered samples with various amounts of NiO at 350 ℃Inset: equivalent circuits at different NiO contents. L1: Inductance due to platinum wire and silver electrode; R0: lead wire resistance; Rg: grain resistance; CPEg: grain capacitance; Rgb: grain boundary resistance; CPEgb: grain boundary capacitance; CPEd1: a double layer capacitance; Rct: charge transition resistance.

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Preparation of NiO Doped Beta-Al₂O₃ Solid Electrolyte via a Low Temperature Combustion Method^†

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