Synthesis of Organodiphosphonate MOFs-derived Ni2P/C Composite†

doi:10.7503/cjcu20170551

Abstract

Abstract:

Ni and organodiphosphonate-based metal organic framework(Ni-MOF) was synthesized under hydrothermal condition using p-xylylenediphosphonate as the organic ligand. Then, Ni-MOF was selected to prepare the amorphous carbon coated Ni₂P composite materials by facile method. The composite material retained the lamellate shape of the precursor, and the BET surface area reached 202 m²/g. The Ni₂P nanoparticles in the composites had good crystallinity, and the particles were homogeneous and had no reunion. In the performance of lithium ion battery, the Ni₂P/C composite structure improved the electron and ion conductivity of the material while reducing the volume expansion of the material, thus improving the electrochemical properties of the material. The first charge and discharge capacity of Ni₂P/C composite material were 247 and 226 mA·h·g^-1, respectively, coulombic efficiency can reach 91.7%, and the coulombic efficiency reaches 100% after 200 cycles.

Key words: Metal-organic framework, Carbonization, Ni2P/C Composite, Lithium ion battery

CLC Number:

O614.81
O646

TrendMD:

XU Dan, XIAO Shanshan, WU Pan, PAN Ying, CHEN Lihua, SU Baolian, XUE Ming, QIU Shilun. Synthesis of Organodiphosphonate MOFs-derived Ni₂P/C Composite^†[J]. Chem. J. Chinese Universities, 2018, 39(1): 19.

Figures/Tables 6

Fig.1 PXRD patterns of Ni-MOF(a) and the simulated(b)(A), 3D framework(B) and SEM image(C) of Ni-MOF and PXRD patterns of NixPy/C carbonized at 600, 700 and 800 ℃(D)

Fig.2 PXRD pattern(A) and SEM image(B) of the Ni2P/C sample

Fig.3 TEM images(A, B), HRTEM image(C), SAED pattern(D), STEM image(E) and elemental mapping of carbon(F), nickel(G) and phosphorus(H) of the Ni2P/C sample

Fig.4 XPS spectra of the Ni2P/C sample(A) Survey spectrum; (B) Ni2p; (C) P2p.

Fig.5 N2 adsorption-desorption isotherms(A) and pore size distribution(B) of the Ni2P/C sample

Fig.6 Charge/discharge curves of Ni2P/C sample during the 200 cycles(A), cycle performance of Ni2P/C sample at a current density of 0.2 C(B), 0.5 C(C) and 1.0 C(D)

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Synthesis of Organodiphosphonate MOFs-derived Ni₂P/C Composite^†

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