Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (6): 1036.doi: 10.7503/cjcu20160111
• Articles: Inorganic Chemistry • Previous Articles Next Articles
CHEN Huajun*(), XI Xiaojing, DING Wuxiu
Received:
2016-02-25
Online:
2016-06-10
Published:
2016-05-26
Contact:
CHEN Huajun
E-mail:chj790118@163.com
Supported by:
CLC Number:
TrendMD:
CHEN Huajun, XI Xiaojing, DING Wuxiu. One-pot Synthesis and Antimicrobial Performance of Metallic Silver-doped Mesoporous Al2O3 Nanoparticles†[J]. Chem. J. Chinese Universities, 2016, 37(6): 1036.
Sample | FWHM,Lattice fringes(d/nm) and peak value[2θ/(°)] | Lattice constant a=b=c/nm | ||
---|---|---|---|---|
(111) Interface | (400) Interface | (440) Interface | ||
Mesoporous Al2O3 NPs | 0.243/4.6156/19.214 | 0.896/1.9730/45.961 | 0.829/1.3942/67.074 | 0.788859 |
Mesoporous Ag/Al2O3 NPs | 0.714/4.5775/19.375 | 0.959/1.9688/46.065 | 0.925/1.3914/67.231 | 0.790039 |
Table 1 FWHM, lattice fringes, peak value and lattice parameters of mesoporous Al2O3 NPs and Ag/Al2O3 NPs
Sample | FWHM,Lattice fringes(d/nm) and peak value[2θ/(°)] | Lattice constant a=b=c/nm | ||
---|---|---|---|---|
(111) Interface | (400) Interface | (440) Interface | ||
Mesoporous Al2O3 NPs | 0.243/4.6156/19.214 | 0.896/1.9730/45.961 | 0.829/1.3942/67.074 | 0.788859 |
Mesoporous Ag/Al2O3 NPs | 0.714/4.5775/19.375 | 0.959/1.9688/46.065 | 0.925/1.3914/67.231 | 0.790039 |
Element | Mass fraction(%) | Atomic fraction(%) |
---|---|---|
O | 36.32 | 56.82 |
Al | 40.84 | 37.88 |
Ag | 22.84 | 5.30 |
Table 2 Results of X-ray fluorescence analysis of mesoporous Ag/Al2O3 NPs
Element | Mass fraction(%) | Atomic fraction(%) |
---|---|---|
O | 36.32 | 56.82 |
Al | 40.84 | 37.88 |
Ag | 22.84 | 5.30 |
Sample | SBET/(m2·g-1) | Vt/(cm3·g-1) | Dp/nm |
---|---|---|---|
Mesoporous Al2O3 NPs | 189.899 | 0.329 | 7.879 |
Mesoporous Ag/Al2O3 NPs | 276.339 | 0.432 | 9.715 |
Table 3 Mesoporous parameters of Al2O3 NPs and Ag/Al2O3 NPs
Sample | SBET/(m2·g-1) | Vt/(cm3·g-1) | Dp/nm |
---|---|---|---|
Mesoporous Al2O3 NPs | 189.899 | 0.329 | 7.879 |
Mesoporous Ag/Al2O3 NPs | 276.339 | 0.432 | 9.715 |
Fig.6 Influence of aeration on bactericidal effect of mesoporous Al2O3 NPs and Ag/Al2O3 NPs against Staphylococcus aureusa. Ag/Al2O3 NPs-O2; b. Ag/Al2O3 NPs-air;c. Ag/Al2O3 NPs-N2; d. Al2O3 NPs-O2.
Antimicrobials concentration/(μg·mL-1) | Escherichia coli | Golden staphylococcus |
---|---|---|
0 | 5.00×107 | 5.00×107 |
20 | 3.80×106 | 4.20×105 |
40 | 9.60×105 | 3.20×104 |
60 | 1.36×103 | 1.06×102 |
80 | 80 | 0 |
Table 4 Antibacterial activity(cfu·mL-1) of mesoporous Ag/Al2O3 NPs on Escherichia coli and Staphylococcus aureus
Antimicrobials concentration/(μg·mL-1) | Escherichia coli | Golden staphylococcus |
---|---|---|
0 | 5.00×107 | 5.00×107 |
20 | 3.80×106 | 4.20×105 |
40 | 9.60×105 | 3.20×104 |
60 | 1.36×103 | 1.06×102 |
80 | 80 | 0 |
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