Ion-transfer Reaction of SO42- Across the Water/1,2-dichloroethane Interface Modified by an Anion Exchange Membrane

doi:10.7503/cjcu20150626

Abstract

Abstract:

In this work, the anion-transfer reaction of highly hydrophilic sulfate across the water/1,2-dichloroethane(W/DCE) interface modified by a homogeneous anion exchange membrane(AEM) was investigated by employing cyclic voltammetry(CV), differential pulse voltammetry(DPV) and chronocoulometry. It was found that the electrochemical window could be extended by the modification of W/DCE interface with such an AEM. In addition, the well-defined CV and DPV curves corresponding to the ion-transfer of highly hydrophilic SO₄^2- could be obtained at the modified W/DCE interface. According to the linear relationship between the peak current of CV and the square root of scan rate, as well as the equation of Randles-Sevik, the diffusion coefficient of SO₄^2- in the membrane containing water is calculated to be about 7.6×10^-8 cm²/s. In addition, the peak current of DPV increases linearly with the concentration of SO₄^2-within the range of 5-25 mmol/L. Moreover, the standard reaction rate constant of the ion-transfer of SO₄^2- at such an AEM-modified W/DCE interface was estimated to be about 1.49×10^-3 cm/s via chronocoulometry.

Key words: Anion exchange membrane, Liquid/liquid interface, Ion transfer, Sulfate

CLC Number:

O646

TrendMD:

WANG Huanhuan, HU Daopan, JIANG Xuheng, ZHANG Yehua, CHEN Yong. Ion-transfer Reaction of SO₄^2- Across the Water/1,2-dichloroethane Interface Modified by an Anion Exchange Membrane[J]. Chem. J. Chinese Universities, 2016, 37(3): 546.

References

[1] Peljo P., Girault H. H., Liquid/Liquid Interfaces, Electrochemistry, John Wiley & Sons, New York, 2012, 1-28
[2] Collins C. J., Arrigan D. W. M., Anal. Bioanal. Chem., 2009, 393, 835-845
[3] Girault H. H., Electroanalytical Chemistry, CRC Press, Boca Raton, 2010, 23, 1-104
[4] Liu S. J., Li Q., Shao Y. H., Chem. Soc. Rev., 2011, 40, 2236-2253
[5] Li Q., Xie S. B., Liang Z. W., Meng X., Liu S. J., Girault H. H., Shao Y. H., Angew. Chem. Int. Ed., 2009, 48, 8010-8013
[6] Yuan Y., Su B., Shao Y. H., Chem. J. Chinese Universities, 2001, 22(11), 1819-1823(袁艺, 苏彬, 邵元华. 高等学校化学学报, 2001, 22(11), 1819-1823)
[7] Chen Y., Su B., Shao Y. H., Chem. J. Chinese Universities, 2003, 24(10), 1834-1837(陈勇, 苏彬, 邵元华. 高等学校化学学报, 2003, 24(10), 1834-1837)
[8] Arrigan D. W. M., Herzog G., Scanlon M. D., Strutwolf J., Electroanalytical Chemistry:A Series of Advances, CRC Press, Boca Raton, 2013, 25, 105-178
[9] Qian Q. S., Wilson G. S., Bowman-James K., Girault H. H., Anal. Chem., 2001, 73, 497-503
[10] Ribeiro J. A., Silva F.,Pereira C. M., Anal. Chem., 2013, 85, 1582-1590
[11] Ribeiro J. A., Silva F., Pereira C. M., Electroanal., 2013, 25(10), 2331-2338
[12] Lu X. Q., Wang T. X., Zhou X. B., Li Y., Wu B. W., Liu X. H., J. Phys. Chem. C, 2011, 115, 4800-4805
[13] Xia H., Qin D. D., Zhou X. B., Liu X. H., Lu X. Q., J. Phys. Chem. C, 2013, 117, 23522-23528
[14] de Eulate E. A., Serls L., Arrigan D. W. M., Anal. Bioanal. Chem., 2013, 405, 3801-3806
[15] Liu Y., Strutwolf J., Arrigan D. W. M., Anal. Chem., 2015, 87, 4487-4494
[16] Stephenson M. J., King A. J., Holmes S. M., Dryfe R. A. W., J. Phys. Chem. B, 2005, 109, 19377-19384
[17] Senthilkumar S., Dryfe R. A. W., Saraswathi R., Langmuir, 2007, 23, 3455-3461
[18] Chen Y., Bian S. J., Gao K.,Cao Y. Y., Wu H. Q., Liu C. X., Jiang X. H., Sun X. L., J. Membr. Sci., 2014, 457, 9-18
[19] Jiang X. H., Gao K., Hu D. P., Wang H. H., Bian S. J., Chen Y., Analyst, 2015, 140, 2823-2833
[20] Hu D. P., Wang H. H., Gao K., Jiang X. H., Wang M., Long Y. F., Chen Y., RSC Adv., 2014, 4, 57035-57040
[21] Sata T., Ion Exchange Membrane:Preparation, Characterization, Modification and Application, The Royal Society of Chemistry, Cambridge, 2004, 215-302
[22] Itoh H., Yoshizumi T., Saeki M., J. Membr. Sci., 1986, 27, 155-163
[23] Shioya T., Nishizawa S., Teramae N., J. Am. Chem. Soc., 1998, 120, 11534-11535
[24] Cui R. F., Li Q., Gross D. E., Meng X., Li B., Marquez M., Yang R. H., Sessler J. L., Shao Y. H., J. Am. Chem. Soc., 2008, 130, 14364-14365
[25] Doyle D. A., Cabral J. M., Pfuetzner R. A., Kuo A., Gulbis J. M., Cohen S. L., Chait B. T., MacKinnon R., Science, 1998, 280, 69-77
[26] Beckstein O., Tai K., Sansom M. S. P., J. Am. Chem. Soc., 2004, 126, 14694-14695
[27] Gouaux E., MacKinnon R., Science, 2005, 310, 1461-1465
[28] Nestor U., Wen H. M., Girma G., Mei Z. Q., Fei W. K., Yang Y., Zhang C. Z., Zhan D. P., Chem. Commun., 2014, 50, 1015-1017
[29] Gao K., Jiang X. H., Hu D. P., Bian S. J., Wang M., Chen Y., Chinese Chem. Lett., 2015, 26, 285-288
[30] Elattar A., Elmidaoui A., Pismenskaia N., Gavach C., Pourcelly G., J. Membr. Sci., 1998, 143, 249-261
[31] Shao Y. H., Mirkin M. V., J. Am. Chem. Soc., 1997, 119, 8103-8104
[32] Li F., Chen Y., Sun P., Zhang M. Q., Gao Z., Zhan D. P., Shao Y. H., J. Phys. Chem. B, 2004, 108, 3295-3302
[33] Huang F., Zhang Z. X., Feng G. D., Yu A. M., Zhang Z. Q., Chem. J. Chinese Universities, 2007, 28(10), 1952-1956(黄峰, 张之鑫, 冯国栋, 于爱民, 张志权. 高等学校化学学报, 2007, 28(10), 1952-1956)
[34] Silver B. R., Holub K., Mareek V., J. Electroanal. Chem., 2014, 731, 107-111
[35] Shao Y. H., Girault H. H., J. Electroanal. Chem., 1990, 282, 59-72
[36] Velickyý M., Tam K. Y., Dryfe R. A. W., J. Electroanal. Chem., 2012, 683, 94-102
[37] Zhao P., Fang H. J., Xue T., Qi X. M., Lu J. X., Acta. Phys. Chim. Sin., 2005, 21(11), 1235-1239(赵鹏, 方慧珏, 薛腾, 亓西敏, 陆嘉星. 物理化学学报, 2005, 21(11), 1235-1239)
[38] Bard A. J., Faulkner L. R., Translated by Shao Y. H., Dong X. D., Zhang B. L., Electrochemical Methods:Fundamentals and Applications, 2rd Edition, Chemical Industry Press, Beijing, 2005, 145-149(Bard A. J., Faulkner L. R.. 邵元华, 董献堆, 张柏林[译]. 电化学方法:原理和应用, 北京:化学工业出版社, 2005, 145-149)

Ion-transfer Reaction of SO₄^2- Across the Water/1,2-dichloroethane Interface Modified by an Anion Exchange Membrane

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