Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (12): 2468.doi: 10.7503/cjcu20150469
• Physical Chemistry • Previous Articles Next Articles
LUO Jinyuan, CHEN Linlin, WANG Yi, LI Hong*()
Received:
2015-06-15
Online:
2015-12-10
Published:
2015-11-19
Contact:
LI Hong
E-mail:lihong@scnu.edu.cn
Supported by:
CLC Number:
TrendMD:
LUO Jinyuan, CHEN Linlin, WANG Yi, LI Hong. Fabrication and Performance of a Novel Visible Light-driven Fuel Cell Based on Photocatalytic Oxidation of Uric Acid by CdS Nanoparticles and Electrocatalytic Reduction of Oxygen by a Copper(Ⅱ) Complex†[J]. Chem. J. Chinese Universities, 2015, 36(12): 2468.
Fig.1 Structure of the Cu(Ⅱ) complex(A) and schematic configuration and electron transfer processes of a photocatalytic UA/O2 fuel cell using CdS/ITO anode and Cu(Ⅱ)/SWCNTs cathode(B)
Fig.3 Effects of visible light(off or on) on open circuit potential(EOC) of CdS/ITO anodes at different UA concentrations c(UA)/(mmol·L-1): a. 0; b. 0.017; c. 0.033; d. 0.057; e. 0.088; f. 0.125; g. 0.189. Inset shows the photovoltage(ΔEOC)-c(UA) plot.
Fig.5 Effects of drying temperature on the photovoltage of CdS/ITO electrode at different UA concentrations c(UA)/(mmol·L-1): a. 0.020; b. 0.041; c. 0.062; d. 0.083; e. 0.123; f. 0.164.
Fig.6 Cyclic voltammograms of Cu(Ⅱ)/SWCNTs electrode in nitrogen-saturated buffer solutions at different scan rates(A), relation of cathodic peak currents with scan rate(B) and change of cathodic peak potentials with natural logarithm of scan rate(C) Scan rate/(V·s-1): a. 0.05; b. 0.10; c. 0.15; d. 0.20; e. 0.25; f. 0.30.
Fig.7 Differential pulse voltammograms of SWCNTs(a) and Cu(Ⅱ)/SWCNTs(b) electrodes in buffer solutions containing saturated O2(A) or 0.2 mmol/L H2O2(B) and of Cu(Ⅱ)/SWCNTs electrode in N2-saturated buffer solutions(c)
Fig.8 Effects of Cu(Ⅱ) concentration on open-circuit potential of CdS/ITO electrode in the absence and presence of visible light Cu(Ⅱ) concentration/(mmol·L-1): a. 0; b. 0.005; c. 0.010; d. 0.016; e. 0.021; f. 0.026; g. 0.031. Inset shows photovoltage vs. Cu(Ⅱ) concentration plot.
Fig.9 Effects of visible light(a) and UV light(b) on open-circuit voltage of 0.2 mmol/L UA/O2 fuel cells employing CdS/ITO anode and Cu(Ⅱ)/SWCNTs cathode
Fig.10 Cell current(a) and power output(b) from 0.2 mmol/L UA/O2 fuel cells using CdS/ITO anode and Cu(Ⅱ)/SWCNTs cathode under the excitation of visible light(A) and UV light(B) by altering the external load from 1000 Ω to 100000 Ω
[1] | Wang C. Y., Liu C. Y., Shen T., Chem. J. Chinese Universities,1998, 19(12), 2013—2019 |
(王传义, 刘春艳, 沈涛. 高等学校化学学报,1998, 19(12), 2013—2019) | |
[2] | Ames B. N., Cathcart R., Scwiers E., Hochstein R., P. Natl. Acad. Sci. USA, 1981, 78(11), 6858—6862 |
[3] | Becker B. F., Free Radical Bio. Med., 1993, 14(6), 615—631 |
[4] | Lesch M., Nyhan W. L., Am. J. Med., 1964, 36(4), 561—570 |
[5] | Rock K. L., Kataoka H., Lai J. J., Nat. Rev. Rheumatol., 2013, 9, 13—23 |
[6] | Tsahar E., Arad Z., Izhaki I., Guglielmo C. G., J. Comp. Physiol. B,2006, 176(7), 653—661 |
[7] | Pumera M., Ambrosi A., Bonanni A., Chng E. L. K., Poh H. L., TrAC-Trend. Anal. Chem., 2010, 29(9), 954—965 |
[8] | Zhang L., Shi Z., Lang Q., J. Solid State Electr., 2011, 15(4), 801—809 |
[9] | Jia S. S., Fei J. J., Zhou J. P., Chen X. M., Meng J. Q., Biosens. Bioelectron., 2009, 24(10), 3049—3054 |
[10] | Goyal R. N., Gupta V. K., Sangal A., Bachheti N., Electroanal., 2005, 17(24), 2217—2223 |
[11] | Ali S. M. U., Alvi N. H., Ibupoto Z., Nur O., Willander M., Danielsson B., Sens. Actuators,2011, 152(2), 241—247 |
[12] | Lu S. J., Luo J. Y., Ji S. B., Li N. X., Li H., Li W. S., Electrochim. Acta,2014, 136(8), 130—137 |
[13] | Lu S. J., Ji S.B., Liu J.C., Li H., Li W. S., J. Power Sources,2015, 273(1), 142—148 |
[14] | Chauhan R., Kumar A., Chaudhary R. P., Appl. Surf. Sci., 2013, 270(4), 655—660 |
[15] | Zhang Q. X., Guo X. Z., Huang X. M., Huang S. Q., Li D. M., Luo Y. H., Shen Q., Toyoda T., Meng Q. B., Phys. Chem. Chem. Phys., 2011, 13(10), 4659—4667 |
[16] | Winter J.O., Gomez N., Gatzert S., Schmidt C. E., Korgel B. A., Colloid Surface A,2005, 254(1), 147—157 |
[17] | Lim B., Jiang M. J., Camargo P. H. C., Cho E. C., Tao J., Lu X. M., Zhu Y. M., Xia Y. N., Science, 2009, 324(5932), 1302—1305 |
[18] | Gong K. P., Du F., Xia Z. H., Durstock M., Dai L. M., Science, 2009, 323(5915), 760—764 |
[19] | Manisankar P., Pushpalatha A. M., Vasanthkumar S., Gomathi A., Viswanathan S., J. Electroanal. Chem., 2004, 571(1), 43—50 |
[20] | Sun H., Yu Z., Yang W. Q., He W. J., Guo Z. J., Chem. J. Chinese Universities,2011, 32(3), 437—450 |
(孙辉, 余臻, 杨玮琪, 何卫江, 郭子建. 高等学校化学学报,2011, 32(3), 437—450) | |
[21] | Li H., Le X. Y., Pang D. W., Deng H., Xu Z. H., Li Z. H., J. Inorg. Biochem., 2005, 99(11), 2240—2247 |
[22] | Liao S.R Le X.Y., Lu Q.M., Liu X. P., Xiong Y. H., Lin Q. B., Journal of South China Agricultural University, 2006, 27(3), 122—124) |
(廖升荣, 乐学义, 卢其明, 刘小平, 熊亚红, 林庆斌. 华南农业大学学报, 2006, 27(3), 122—124) | |
[23] | Sasikala G., Dhanasekaran R., Subramanian C., Thin Solid Films,1997, 302(1), 71—76 |
[24] | Kim D. J., Hahn S. H., Oh S. H., Kim E. J., Mater. Lett., 2002, 57(2), 355—360 |
[25] | Hurum D.C., Agrios A.G., Gray K.A., Rajh T., Thurnauer M. C., J. Phys. Chem. B,2003, 107(19), 4545—4549 |
[26] | Wang X. L., Chao H., Li H., Hong X. L., Ji L. N., Li X. Y., J. Inorg. Biochem., 2004, 98(3), 423—429 |
[27] | Banham D., Ye S., Pei K., Ozaki J., Kishimoto T., Imashiro Y., J. Power Sources,2015, 285(7), 334—348 |
[28] | Huang H. B., Zeng X. P., Li W., Wang H., Wang Q., Yang Y. J., J. Mater. Chem. A,2014, 2, 16516—16522 |
[29] | Munir A., Shah A., Shah A. H., Rana U. A., Adhikari B., Khan S. B., Qureshi R., Kraatz H. B., J. Electrochem. Soc., 2014, 161(6), H370—H374 |
[30] | Laviron E., J. Electroanal. Chem. Interfacial Electrochem., 1979, 101(1), 19—28 |
[31] | Shakkthivel P., Chen S., Biosens. Bioelectron., 2007, 22(8), 1680—1687 |
[32] | Dong S.J., Liu Y., Biosens. Bioelectron., 2007, 23(4), 593—597 |
[33] | Shimazaki Y., Yajima T., Takani M., Yamauchi O., Coord. Chem. Rev., 2009, 253(3/4), 479—492 |
[34] | Thorseth M. A., Tornow C. E., Tse E. C. M., Gewirth A. A., Coord. Chem. Rev., 2013, 257(1), 130—139 |
[35] | Zhou W. P., Cao Z. C., Jiang S. H., Huang H. Y., Deng L. J., Liu Y. J., Shen P., Zhao B., Tan S. T., Zhang X. X., Org. Electron., 2012, 13(4), 560—569 |
[36] | Oncescu V., Erickson D., J. Power Sources,2011, 196(22), 9169—9175 |
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