Synthesis and Properties of Polyimides Containing Benzimidazole Group

doi:10.7503/cjcu20130414

Abstract

Abstract:

A diamine monomer containing benzimidazole unit 2-(4-aminophenyl)-4-aminobenzimidazole was polymerized with commercially available dianhydrides to obtain polyimide films. The results of thermal and mechanical properties characterization show that these polyimide films possess considerable thermal resistance and good mechanical properties. Meanwhile, the relative position of the amino group in the diamine monomer imparts bent and distorted conformation of the polyimides, leading to good thermal plasticity and large value of coefficient of thermal expansion.

Key words: Polyimide, Benzimidazole, Thermal resistance, Thermal plasticity

CLC Number:

O631

TrendMD:

ZHOU Yu, WANG Da-Ming, ZHAO Xiao-Gang, ZHOU Hong-Wei, CHEN Chun-Hai, DANG Guo-Dong. Synthesis and Properties of Polyimides Containing Benzimidazole Group[J]. Chem. J. Chinese Universities, 2013, 34(10): 2427.

References

[1] Song N. H., Gao L. X., Ding M. X., Chem. J. Chinese Universities, 1999, 20(5), 803—808(宋乃恒, 高连勋, 丁孟贤. 高等学校化学学报, 1999, 20(5), 803—808)

[2] Matsuura T., Hasuda Y., Nishi S., Yamada N., Macromolecules, 1991, 24, 5001—5005

[3] Li P., Chen C. H., Wang D. J., Zhou H. W., Zhao X. G., Dang G. D., Chem. J. Chinese Universities, 2010, 31(1), 212—214(李鹏, 陈春海, 王冬佶, 周宏伟, 赵晓刚, 党国栋. 高等学校化学学报, 2010, 31(1), 212—214)

[4] Hasagawa M., Koseki K., High Perform. Polym., 2006, 18(5), 697—717

[5] Yang M., Paek C., Zhou H. W., Chen C. H., Dang G. D., Chem. J. Chinese Universities, 2012, 33(9), 2117—2120(杨明, 白哲革, 周宏伟, 陈春海, 党国栋. 高等学校化学学报, 2012, 33(9), 2117—2120)

[6] Wang X., Zhang P., Chen C. H., Li P.,Wang D. J., Dang G. D., Chem. J. Chinese Universities, 2010, 31(11), 2289—2292(王响, 张鹏, 陈春海, 李鹏, 王冬佶, 党国栋. 高等学校化学学报, 2010, 31(11), 2289—2292)

[7] Coburn J.C., Soper P. D., Auman B. C., Macromolecules, 1995, 28(9), 3253—3260

[8] Liaw D. J., Wang K. L., Huang Y. C., Lee K. R., Lai J. Y., Ha C. S., Prog. Polym. Sci., 2012, 37(7), 907—974

[9] Allen S. R., Filippov A. G., Farris R. J., Thomas E. L., Wong C. P., Berry G. C., Chenevey E. C., Macromolecules, 1981, 14(4), 1135—1138

[10] Wang S., Zhou H. W., Dang G. D., Chen C. H., J. Polym. Sci. Part A:Polym. Chem., 2009, 47(8), 2024—2031

[11] Arunbabu D., Sannigrahi A., Jana T., J. Phys. Chem. B, 2008, 112(17), 5305—5310

[12] Sensui N., Ishii J., Takata A., Oami Y., Hasegawa M., Yokota R., High Perform. Polym., 2009, 21(6), 709—728

[13] Hyon H., Paek C., Dang G. D., Zhao X. G., Zhou H. W., Chen C. H., Chem. J. Chinese Universities, 2009, 30(10), 2104—2106(玄学民, 白哲革, 党国栋, 赵晓刚, 周宏伟, 陈春海. 高等学校化学学报, 2009, 30(10), 2104—2106)

[14] Hasegawa M., Sensui N., Shindo Y., Yokota R., Macromolecules, 1999, 32(2), 387—396

[15] Zhou H. W., Chen C. H., Kanbara R., Sasaki T., Yokota R., High Perform. Polym., 2005, 17(2), 193—212

[16] Hasegawa M., High Perform. Polym., 2001, 13(2), S93—S106

[17] Hasegawa M., Matano T., Shindo Y., Sugimura T., Macromolecules, 1996, 29(24), 7897—7909

[18] Hasegawa M., Sensui N., Shindo Y., Yokota R., J. Polym. Sci. Part B:Polym. Phys., 1999, 37(17), 2499—2511

[19] Hasegawa M., Horie K., Prog. Polym. Sci., 2001, 26, 259—335

[20] Ree M., Nunes T. L., Czornyj G., Volksen W., Polymer, 1992, 33(6), 1228—1236

[21] Chen C. H., Yokota R., Hasegawa M., Kochi M., Horie K., Hergenrother P., High Perform. Polym., 2005, 17(3), 317—333