Melt Processing of PVA with Magnesium Chloride and Polyethylene Glycol as the Complex Plasticizer

doi:10.7503/cjcu20130109

Abstract

Abstract:

Poly(vinyl alcohol)(PVA) samples were prepared through the melt processing by employing magnesium chloride and polyethylene glycol(PEG) as the complex plasticizer. The interaction between the complex plasticizer and PVA was investigated by Fourier transform infrared spectroscopy(FTIR). The influences of the complex plasticizer on the crystalline and thermal properties were studied by X-ray diffraction(XRD), differential scanning calorimetry(DSC) and thermogravimetric analysis(TGA), respectively. The results show that the plasticizer can effectively destroy the hydrogen bonding between PVA molecules. The crystallinity of PVA decreased rapidly with the addition of the complex plasticizer. Thermal measurements show that the melting point(T_m) of PVA decreases, the thermal stability improves and thus the thermal processing of PVA are achieved. The obtained PVA film shows good mechanical property, with the tensile strength of 31 MPa and the elongation at break of 466%.

Key words: Poly(vinyl alcohol), Complex plasticizer, Magnesium chloride hexahydrate, Polyethylene glycol, Mechanical property

CLC Number:

O632.31

TrendMD:

JIANG Xian-cai, SONG Jie, JIANG Ting, DAI Hua, ZHANG Xi. Melt Processing of PVA with Magnesium Chloride and Polyethylene Glycol as the Complex Plasticizer[J]. Chem. J. Chinese Universities, 2013, 34(10): 2451.

References

[1] Yan R. X., Water Soluble Polymer, Chemical Industry Press, Beijing, 1998, 42(严瑞瑄. 水溶性高分子, 北京:化学工业出版社, 1998, 42)

[2] Jin G., Yao Q. Z., Zhang L., Chem. Res. Chinese Universities, 2008, 24(2), 154—161

[3] Liu L. L., Zhang J., Qiao J. L., Chem. J. Chinese Universities, 2012, 33(8), 1842—1849(刘玲玲, 张璟, 乔锦丽. 高等学校化学学报, 2012, 33(8), 1842—1849)

[4] Xia H. Y., He G., Gao L. N., Peng J. X., Fang Y., Chem. J. Chinese Universities., 2010, 31(8), 1614—1619(夏慧芸, 何刚, 高莉宁, 彭军霞, 房喻. 高等学校化学学报, 2010, 31(8), 1614—1619)

[5] Jiang X. C., Dong H.Y., Xie J. S., Zhang X., Dai H., Polymer Bulletin, 2010, 10, 38—45(江献财, 董海亚, 谢静思, 张熙, 代华. 高分子通报, 2010, 10, 38—45)

[6] Chen N., Li L., Wang Q., Plast. Rubber. Compos., 2007, 36, 283—290

[7] Wang R., Wang Q., Li L., Polym. Int., 2003, 52, 1820—1826

[8] Zhang H., Wang Q., Li L., Polym. Int., 2009, 58, 97—104

[9] Jang J., Lee D. K., Polymer, 2003, 44(26), 8139—8146

[10] Meng X. S., Wang P., Mao G. J., Wang C., Journal of Harbin University of Technology, 2007, 39(8), 1276—1279(孟祥胜, 王鹏, 毛桂洁, 王冲. 哈尔滨工业大学学报, 2007, 39(8), 1276—1279)

[11] Li Y. D., Bai B. F., Wei S., Cao S. K., Song H. D., China Plastics Industry, 2008, 36(12), 38—41(李亚东, 白宝丰, 魏松, 曹少魁, 宋华栋. 塑料工业, 2008, 36(12), 38—41)

[12] Xiang A. M., Liu W. C., Zhao Q. H., Kang Z. N., China Plastics, 2003, 17(2), 60—62(项爱民, 刘万蝉, 赵启辉, 康智能. 中国塑料, 2003, 17(2), 60—62)

[13] Jiang X. C., Xu W. P., Tang Y. D., Zhang X., Dai H., Acta Polymerica Sinica, 2010, 9, 1143—1147(江献财, 徐文萍, 唐宴东, 张熙, 代华. 高分子学报, 2010, 9, 1143—1147)

[14] Yamaura K., Naito M., J. Mater. Sci., 2002, 37, 705—708

[15] Zidan H. M., J. Appl. Polym. Sci., 2003, 88, 516—521

[16] Abdelaziz M., J. Appl. Polym. Sci., 2004, 94, 2178—2186

[17] Bhajantri R. F., Ravindrachary V., Harisha A., Crasta V., Nayak S. P., Poojary B., Polymer, 2006, 47, 3591—3598

[18] Kubo J. I., Rahman N., Takahashi N., Kawai T., Matsuba G., Nishida K., Kanaya T., Yamamoto M., J. Appl. Polym. Sci., 2009, 112(3), 1647—1652

[19] Jiang X. C., Liu L., Xia C., Zhang X., Dai H., Polymer Materials Science and Engineering, 2011, 27(1), 127—134(江献财, 刘磊, 夏超, 张熙, 代华. 高分子材料科学与工程, 2011, 27(1), 127—134)

[20] Jiang X. C., Xia C., Ye D. Z., Liu L., Dai H., Zhang X., Chem. J. Chinese Universities, 2012, 33(8), 1872—1876(江献财, 夏超, 叶德展, 刘磊, 代华. 高等学校化学学报, 2012, 33(8), 1872—1876)

[21] Ning Y. C., Structural Identification of Organic Compounds and Organic Spectroscopy, Science Press, Beijing, 2008, 332(宁永成. 有机化合物结构鉴定与有机波普学, 北京:科学出版社, 2008, 332)

[22] Zou S. L., He J. Y., Yang R. J., Polymer Materials Science and Engineering, 2008, 24(5), 84—87(邹石龙, 何吉宇, 杨荣杰. 高分子材料科学与工程, 2008, 24(5), 84—87)