Trehalose-modified Poly（vinyl alcohol） and Their Antifogging/Antifrosting Coatings

doi:10.7503/cjcu20210060

Abstract

Abstract:

Trehalose-grafted poly（vinyl alcohol）（PVA-g-Tre） was synthesized from carboxylated trehalose and poly（vinyl alcohol）（PVA）， and the hydrophilic semi-interpenetrating polymer network antifogging/ antifrosting coatings were further prepared from the trehalose-modified polymer with ethylene glycol dimethacrylate via photoinitiated polymerization. The chemical structure of PVA-g-Tre was characterized by proton nuclear magnetic resonance and Fourier transform infrared spectroscopy. The roughness and wettability of the coating surface as well as hydrogen bonding between water and the polymer were analyzed by atomic force microscopy， water contact angle and Raman spectroscopy， respectively. The transmittance， antifogging and antifrosting properties of the coatings were measured. Results showed that the prepared coatings containing PVA-g-Tre with different trehalose-grafting ratios had low surface roughness with high transmittance. Compared with the PVA coating， the PVA-g-Tre coatings exhibited excellent antifogging and antifrosting properties due to the enhanced hydrophilicity and wettability by introduction of trehalose.

Key words: Poly（vinyl alcohol）, Trehalose, Grafted modification, Antifogging coating, Antifrosting coating

CLC Number:

O631

TrendMD:

BAI Jingqi, BAI Shan, REN Lixia, ZHU Kongying, ZHAO Yunhui, LI Xiaohui, YUAN Xiaoyan. Trehalose-modified Poly（vinyl alcohol） and Their Antifogging/Antifrosting Coatings[J]. Chem. J. Chinese Universities, 2021, 42(8): 2683.

Figures/Tables 8

References 27

1	Wong C.Y.， Wong W. Y.， Loh K. S.， Daud W. R. W.， Lim K. L.， Khalid M.， Walvekar R.， Polym. Rev.， 2020， 60（1）， 171—202
2	Feldman D.， J. Compos. Sci.， 2020， 4， 175
3	Yan M.， Zhou W. D.， Zhang H.， Shi J. F.， Zhao Y. H.， Ye Y. M.， Guo J.， Yu Y.， Chem. J. Chinese Universities， 2020， 41（2）， 349—357（闫铭，周炜东，张鸿，石军峰，赵云鹤，叶泳铭，郭静，于跃. 高等学校化学学报， 2020， 41（2）， 349—357）
4	Wang X.， Li L.， Chen N.， Wang Q.， Chem. J. Chinese Universities， 2012， 33（4）， 813—817（王郗，李莉，陈宁，王琪. 高等学校化学学报， 2012， 33（4）， 813—817）
5	Liu Y.， Hu H. Y.， Yang X. L.， Lv J.， Zhou L.， Luo Z. K.， Biomed. Mater.， 2019， 14， 055009
6	Jiang C. H.， Wang H. Y.， Qi L.， Gao G. T.， Chem. J. Chinese Universities， 2013， 34（1）， 231—235（蒋春花，王宏宇，齐力，高桂天. 高等学校化学学报， 2013， 34（1）， 231—235）
7	Zhu Z. P.， Zheng S.， Peng S.， Zhao Y.， Tian Y.， Adv. Mater.， 2017， 29（45）， 1703120
8	Lee H.， Alcaraz M. L.， Rubner M. F.， Cohen R. E.， ACS Nano， 2013， 7（3）， 2172—2185
9	Li Y. X.， Fang X.， Wang Y.， Ma B. H.， Sun J. Q.， Chem. Mater.， 2016， 28（19）， 6975—6984
10	Wang W.， Lu P. P.， Fan Y.， Tian L. M.， Niu S. C.， Zhao J.， Ren L. Q.， Chem. Eng. J.， 2019， 378， 122173
11	Zhao J.， Meyer A.， Ma L.， Ming W. H.， Chem. Commun.， 2013， 49（100）， 11764—11766
12	Bai S.， Li X. H.， Zhang R. C.， Li C.， Zhu K. Y.， Sun P. C.， Zhao Y. H.， Ren L. X.， Yuan X.Y.， Chem. Eng. J.， 2019， 357（1）， 667—677
13	Li C.， Li X. H.， Tao C.， Ren L. X.， Zhao Y. H.， Bai S.， Yuan X. Y.， ACS Appl. Mater. Interfaces， 2017， 9（27）， 22959—22969
14	Bai S.， Li X. H.， Zhao Y. H.， Ren L. X.， Yuan X. Y.， ACS Appl. Mater. Interfaces， 2020， 12（10）， 12305—12316
15	Zhao C. X.， Yuan X. Y.， Bai S.， Sun P. C.， Zhao Y. H.， Zhu K. Y.， Ren L. X.， Li X. H.， Sci. China Technol. Sc.， 2020， DOI： 10.1007/s11431-020-1699-3
16	Luo S.， Qiao X.， Wang Q. Y.， Zhang Y. F.， Fu P.， Lin Z. D.， Du F. P.， Cheng C.， J. Mater. Sci.， 2019， 54（7）， 5961—5970
17	Wu G. Q.， Yang Y. L.， Lei Y. T.， Fu D. P.， Li Y. C.， Zhen Y. H.， Teng M. Y.， J. Coat. Technol. Res.， 2020， 17（5）， 1145—1155
18	Nishiyabu R.， Takahashi Y.， Yabuki T.， Gommori S， Yamamoto Y.， Kitagishi H.， Kubo Y.， RSC Adv.， 2020， 10（1）， 86—94
19	Paneru R.， Lamichhane P.， Adhikari B. C.， Ki S. H.， Choi J.， Kwon J. S.， Choi E. H.， AIP Advances， 2019， 9， 075008
20	Mancini R. J.， Lee J.， Maynard H. D.， J. Am. Chem. Soc.， 2012， 134（20）， 8474—8479
21	O’Shea T. M.， Webber M. J.， Aimetti A. A.， Langer R.， Adv. Healthcare Mater.， 2015， 4（12）， 1802—1812
22	Huang H. S.， Zhao G.， Zhang Y.T， Xu J. S.， Toth T. L.， He X. M.， ACS Biomater. Sci. Eng.， 2017， 3（8）， 1758—1768
23	Kolosova O. Y.， Kurochkin I. N.， Kurochkin I. I.， Lozinsky V. I.， Eur. Polym. J.， 2018， 102， 169—177
24	Koushik D.， Nibedita P. ， Brijesh K.， Nihar R. J.， Nikhil R. J.， ACS Appl. Mater. Interfaces， 2017， 9（28）， 24126—24139
25	Liu B.， Zhang Q. F.， Zhao Y. H.， Ren L. X.， Yuan X. Y.， J. Mater. Chem. B， 2019， 7（37）， 5695—5703
26	Guo X. L.， Li F. M.， Zhang S. L.， Acta Polym. Sin.， 2001，（3）， 408—411（郭兴林，李福绵，张树霖，高分子学报， 2001，（3）， 408—411）
27	Li H. J.， Stanwix P.， Aman Z.， Johns M.， May E.， Wang L. G.， J. Phys. Chem. A， 2016， 120（3）， 417—424

[1]	ZHANG Yong, XU Jun, BAO Yu, CUI Shuxun. Quantifying the Degree of Weakening Effect of Nonpolar Organic Solvent on the Strength of Intramolecular Hydrogen Bonding by Single-molecule Force Spectroscopy [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210863.
[2]	WANG Jie, LI Ying, SHAO Liang, BAI Yang, MA Zhonglei, MA Jianzhong. Preparation and Properties of Poly（vinyl alcohol）/polypyrrole Composite Conductive Hydrogel Strain Sensor [J]. Chem. J. Chinese Universities, 2021, 42(3): 929.
[3]	REN Chenrui, LIU Genqi, QIN Xiatong, LIU Chenhui, FAN Xiaodong. Preparation of PVA Two-dimensional Photonic Crystal Hydrogel and Its Responsive Behavior to Ethanol^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1520.
[4]	LIU Ziyi, XU Miaojun, WANG Qi, LI Bin. Preparation and Properties of Flame Retardant Cotton Fabric by Surface Chemical Grafted Modification [J]. Chem. J. Chinese Universities, 2017, 38(8): 1477.
[5]	PAN Qi, LI Daixi, GUO Baisong, YANG Chunsheng, YANG Zhi. Active Structure Protection of Monoclonal Antibody Fusion Protein Etanercept^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 274.
[6]	WANG Huan, CHEN Ning, WANG Qi. Interaction Between β-Tricalcium Phosphate and Poly(vinyl alcohol) and Its Effect on the Thermal and Mechanical Properties of Poly(vinyl alcohol)^† [J]. Chem. J. Chinese Universities, 2014, 35(8): 1810.
[7]	ZHANG Meng-Juan, FEI Xu, TIAN Jing, FAN Shu-Qi, WANG Yi. Preparation of Interpenetrating Network Polyvinyl Alcohol Composite Coatings for Solid-phase Microextraction [J]. Chem. J. Chinese Universities, 2013, 34(3): 698.
[8]	JIANG Xian-cai, SONG Jie, JIANG Ting, DAI Hua, ZHANG Xi. Melt Processing of PVA with Magnesium Chloride and Polyethylene Glycol as the Complex Plasticizer [J]. Chem. J. Chinese Universities, 2013, 34(10): 2451.
[9]	JIANG Ting, JIANG Xian-Cai, ZHANG Xiao-Fei, DAI Hua, ZHANG Xi. Preparation and Properties of Starch/Poly(vinyl alcohol) Film Plasticized by Magnesium Nitrate Hexahydrate [J]. Chem. J. Chinese Universities, 2012, 33(12): 2822.
[10]	LIU Ling-Ling, ZHANG Jing, QIAO Jin-Li. Synthesis and Properties of PVA/QHECE/PEG Anion-exchange Membranes for Potential Fuel Cells [J]. Chem. J. Chinese Universities, 2012, 33(08): 1842.
[11]	JIANG Xian-Cai, XIA Chao, YE De-Zhan, LIU Lei, DAI Hua, ZHANG Xi. Properties of Poly(vinyl alcohol) Plasticized by Magnesium Chloride [J]. Chem. J. Chinese Universities, 2012, 33(08): 1872.
[12]	SHI Hai-Feng, LI Jian-Hua, YIN Yi-Ping, ZHANG Xing-Xiang, WANG Du-Jin. Synthesis, Structure and Thermal Properties of Poly(vinyl alcohol)-g-isocyanate-fatty Alcohol Comb Copolymers [J]. Chem. J. Chinese Universities, 2012, 33(07): 1613.
[13]	WANG Xi, LI Li, CHEN Ning, WANG Qi. Effect of Hydrogen Bonding on Water States in Sorbitol Modified PVA System [J]. Chem. J. Chinese Universities, 2012, 33(04): 813.
[14]	FU Jing, QIAO Jin-Li*, MA Jian-Xin. Preparation and Stability of Quaternary Ammonium Based Solid Alkaline Electrolyte Membrane for Fuel Cells [J]. Chem. J. Chinese Universities, 2011, 32(7): 1598.
[15]	ZHAO Liang, TANG Gong-Wen, SU Jun-Feng, HAO Xin, ZHANG Yuan, SHI Chen-Lu, JIANG . Electrospinning of Soy Protein Isolate/Poly(vinyl alcohol) [J]. Chem. J. Chinese Universities, 2010, 31(4): 811.