高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (10): 1533.

• 论文 •    下一篇

一个含铜(Ⅱ)四氮大环阳离子和锰(Ⅱ)一维链阴离子化合物{[Cu(trans[14]diene)SCN]2Mn(SCN)4(4,4'-bipy)·4H2O}n的合成和结构

沈昊宇1, 孙柏旺1, 廖代正1, 姜宗慧1, 阎世平1, 王耕霖1, 郁开北2   

  1. 1. 南开大学化学系, 天津, 300071;
    2. 中国科学院成都分院分析测试中心, 成都, 610041
  • 收稿日期:1997-10-16 出版日期:1998-10-24 发布日期:1998-10-24
  • 通讯作者: 廖代正
  • 作者简介:沈昊宇,女,26岁,博士研究生.
  • 基金资助:

    国家自然科学基金(批准号:129571018,59572040)和高等学校博士点专项基金资助课题.

Synthesis and Structure of a New 4,4'-Bipy-bridged One Dimensional Hetero-metallic Compound with Macrocycle Ligand {[Cu(trans[14]diene)SCN]2Mn(SCN)4(4,4'-bipy)·4H2O}n

SHEN Hao-Yu1, SUN Bai-Wang1, LIAO Dai-Zheng1, JIANG Zong-Hui1, YAN Shi-Ping1, WANG Geng-Lin1, YU Kai-Bei2   

  1. 1. Department of Chemistry, Nankai University, Tianjin, 300071;
    2. Analysis Center, Chengdu Branch of Academy of Sciences, Chengdu, 610041
  • Received:1997-10-16 Online:1998-10-24 Published:1998-10-24

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摘要： 报道了一维化合物{[Cu(trans[14]diene)SCN]2Mn(SCN)4(4,4'-bipy)·4H2O}n(trans[14]diene为5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂十四环-4,11-二烯,4,4'-bipy为4,4'-联吡啶)的合成、表征和结构分析.该晶体属三斜晶系,具有P1空间群.α＝0.95920(10)nm,b＝1.06800(10)nm,c＝1.7316(2)nm,α＝84.400(10)°,β＝74.850(10)°,γ＝69.650(10)°,V＝1.6053(3)nm3,Z＝1,Dc＝1.365g/cm3,F(000)＝691,最终R[I＞2σ(I)]＝0.0474,R(全部)＝0.0625,GOF(F2)＝1.222.该化合物含[Mn(SCN)4(4,4'-bipy)n]2-链和两个[Cu(trans[14]diene)SCN]+阳离子.

关键词: 一维结构, 大环配体, 4, 4'-联吡啶桥基

Abstract: The studies of one dimensional compounds have attracted chemists for many interests, because they are not only important for molecular designing and magnetic materials, but also the basis of studying high dimensional compounds.

Key words: One dimensional structure, Macrocycle ligand, 4,4'-Bipy bridging group

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