高等学校化学学报

高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (10): 1585.

• 论文 • 上一篇    下一篇

某些稀土硝酸盐与N,N-二亚水杨基乙二胺-二甲基亚砜三元配合物的合成和晶体结构

孔繁荣, 宗瑞发, 乔赤兵, 张敏, 丁辰元   

  1. 首都师范大学化学系, 北京 100037
  • 收稿日期:1996-09-10 出版日期:1997-10-24 发布日期:1997-10-24
  • 通讯作者: 孔繁荣, 女, 56岁, 副教授.
  • 作者简介:孔繁荣, 女, 56岁, 副教授.
  • 基金资助:

    北京市教育委员会科学基金

Synthesis and Crystal Structure of Some Rare Earth Nitrate Complexes with N, N-Disalicylideneethylenediamine,Dimethyl Sulfoxide

KONG Fan-Rong, ZONG Rui-Fa, QIAO Chi-Bing, ZHANG Min, DING Chen-Yuan   

  1. Department of Chemistry, Capital Normal University, Beijing 100037
  • Received:1996-09-10 Online:1997-10-24 Published:1997-10-24

PDF (PC)

被引次数

13

摘要： 合成了Tb(Ⅲ)、Y(Ⅲ)、Nd(Ⅲ)硝酸盐与N,N-二亚水杨基乙二胺、二甲基亚观的配合物[RE(C6H4OHCHNC2H4NCHC6H4OH)(NO3)3(CH3SOCH3)］.Tb(Ⅲ)配合物晶体为单斜晶系,空间群P21/n,a=0.9628(3)nm,b=1.6439(4)nm,C=1.6256(2)nm,β=102.78(2)°,V=2.509(2)nm3,Dx=1.830g/cm3,Z=4,μ=2.996mm-1,F(000)=1368,R=0.043,Rw=0.046.Tb(Ⅲ)的配位数是9,配位几何为单帽四方反核柱.所有的配位原子都是氧原子.两个中心离子被双Schiff碱桥联,形成一维无限长链.

关键词: 稀土, 配合物, N, N-二亚水杨基乙二胺, 二甲基亚砜, 晶体结构

Abstract: The complexes of Tb (Ⅲ), Y (Ⅲ), Nd (Ⅲ) nitrate with N, N-disalicylideneethylenediamine, dimethyl sulfoxide as the ligands were synthesized. Their molecularcomposition are [RE(C6H5OHCHNC2H4NCHC6H5OH) (NO3)3 (CH3SOCH3)]. The molecularstructures of the complexes were determined by X-ray diffraction. The crystal of Tb (Ⅲ)complex is monoclinic with space group P21/n, a=0.9628 (3) nm, b=1.6439 (4) nm,c=1.6256(2) nm, β=102.78(2), V=2.509(2)nm3, Dx=1.830 g/cm3, Z=4, p=2. 996mm-1, F (000)=1638, R=0. 043, Rw=0. 046. The coordination number of Tb (Ⅲ) is 9 with the geometry of a monocapped square antiprism. All of coordination atoms are oxygenatoms. The two central ions were bridged by the two Schiff base, resulting in an infinitechain.

Key words: Rare earth, Complex,N,N-Disalicylideneethylenediamine, Dimethyl sulfoxide, Crystal structure

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