高等学校化学学报

高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (6): 1010.

• 研究简报 • 上一篇    下一篇

新型杂多化合物[(CH3CH2)4N]4H3O·{Na[(HMo2O5)3(HPO4)(H2PO4)3]2}·(H2PO4)2·10H2O的水热合成与晶体结构

张宏1, 许林1, 王恩波1, 胡长文1, 陈久桐2, 姚元根2, 覃业燕2   

  1. 1. 东北师范大学化学学院多酸化学研究所, 长春 130024;
    2. 中国科学院福建物质结构研究所, 福州 350002
  • 收稿日期:2001-08-03 出版日期:2002-06-24 发布日期:2002-06-24
  • 通讯作者: 王恩波(1936年出生),男,教授,博士生导师,从事多酸化学研究.
  • 基金资助:

    国家自然科学基金(批准号:20171010);中国科学院福建物质结构研究所基金资助

Hydrothermal Synthesis and Crystal Structure of a New Polyoxometalate [(CH3CH2)4N]4H3O{Na[(HMo2O5)3(HPO4)(H2PO4)3]2}·(H2PO4)2·10H2O

ZHANG Hong1, XU Lin1, WANG En-Bo1, HU Chang-Wen1, CHEN Jiu-Tong2, YAO Yuan-Gen2, QIN Ye-Yan2   

  1. 1. Institute of Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
    2. Fujian Institute of Rsearch on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
  • Received:2001-08-03 Online:2002-06-24 Published:2002-06-24

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关键词: 钼磷多金属氧酸盐, 夹心结构, 水热合成, 晶体结构

Abstract: The title compound [(CH3CH2)4N] 4H3O{Na[(HMo2O5)3(HPO4)(H2PO4)3]2}·(H2PO4)2·10H2Owas synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion of the title compound shows a P1 symmetry sandwich structure. The crystal is triclinic, space group P1 with a=15.1513(2) nm, b=15.8517(10) nm, c=23.0251(10) nm, α-= 89.00(1)°, β-=80.09(3)°, γ = 74.30(2)°, V=5.24190(8) nm3, Z=2, Dc=2.105 g/cm3, F(000)=3270, S =1.039, μ =1. 655 mm-1.

Key words: Molybdophosphates, Sandwich structure, Hydrothermal synthesis, Crystal structur

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