高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (1): 19.

• 研究快报 • 上一篇    下一篇

C60(OH)x的简便合成及性质

孙大勇, 刘子阳, 郭兴华, 佘益民, 周雨, 刘淑莹   

  1. 中国科学院长春应用化学研究所应用谱学开放实验室, 长春 130022
  • 收稿日期:1995-09-05 出版日期:1996-01-24 发布日期:1996-01-24
  • 通讯作者: 刘子阳
  • 作者简介:孙大勇,男,25岁,博士研究生.
  • 基金资助:

    国家自然科学基金;中国科学院应用谱学开放实验室和延边敖东药业集团公司资助

Convenient Preparation and Properties of C60(OH)x

SUN Da-Yong, LIU Zi-Yang, GUO Xing-Hua, SHE Yi-Min, ZHOU Yu, LIU Shu-Yhg   

  1. The Key Laboratory of Applied Spectroscopy, Changchun Institute of Applied Chemistry, Chines Academy of Sciences, Changchun 130022
  • Received:1995-09-05 Online:1996-01-24 Published:1996-01-24

PDF (PC)

关键词: C60, 水溶性富勒醇, 钾, 不稳定性, 溶解度

Abstract: In this paper,we introduce a very convenient method to produce water soluble C60derivatives──fullerols by the reaction of C60 with potassium in toluene solution. FT-IR,1HNMRand FABMSproved the multi-hydroxyl and C60 cage structures of the products, Theproperties of unstability to light,heat, basicity of aqueous solution and the solubility insome common polar solvents were also described.

Key words: C60, Water-soluble fullerols, Potassium, Unstability, Solubility

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