高等学校化学学报

高等学校化学学报

• 综合评述 • 上一篇    

具有聚集诱导发光性质的氢键有机框架的研究进展

杨湛,邓皇俊,池振国   

  1. 五邑大学环境与化学工程学院
  • 收稿日期:2026-01-04 修回日期:2026-01-26 网络首发:2026-02-01 发布日期:2026-02-01
  • 通讯作者: 邓皇俊 E-mail:denghj23@mail.sysu.edu.cn
  • 基金资助:
    国家自然科学基金(批准号：52303250，52473195，52403245)及广东省教育厅高校科研平台及项目(批准号：2024KCXTD009，2024ZDJS037，2024KQNCX031)资助

Research Progress on Hydrogen-Bonded Organic Frameworks with Aggregation-Induced Emission

YANG Zhan, DENG Huangjun*, CHI Zhenguo*   

  1. School of Environmental and Chemical Engineering, Wuyi University
  • Received:2026-01-04 Revised:2026-01-26 Online First:2026-02-01 Published:2026-02-01
  • Supported by:
    Supported by the National Natural Science Foundation of China(Nos.52303250, 52473195, 52403245) and Scientific Research Platforms and Projects of University of Department of Education of Guangdong Province (Nos. 2024KCXTD009, 2024ZDJS037, 2024KQNCX031)

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摘要： 氢键有机框架（HOFs）是一类由分子间氢键自组装形成的新型多孔晶态材料，具有高结晶度、结构可调性、动态可逆性以及可功能化等优点，在气体吸附与分离、化学传感及光电功能材料等领域展现出良好的应用前景. 然而，传统有机发光材料在固态或高聚集状态下普遍存在聚集导致发光猝灭（ACQ）效应，发光效率显著降低，严重制约了其在固态发光与器件中的进一步应用. 近年来，将聚集诱导发光（AIE）特性引入HOFs体系，被证明是一种克服ACQ效应并提升固态发光性能的有效策略. 本文综述了近年来具有AIE特性的荧光型与磷光型HOFs的研究进展，重点总结其结构设计思路、发光机理及相关应用探索，并对该领域面临的挑战与发展方向进行了简要展望.

关键词: 聚集诱导发光, 氢键有机框架, 荧光, 磷光

Abstract: Hydrogen-bonded organic frameworks (HOFs) are an emerging class of porous crystalline materials constructed through intermolecular hydrogen-bond self-assembly. Owing to their high crystallinity, structural tunability, dynamic reversibility, and facile functionalization, HOFs have shown considerable potential in gas adsorption and separation, chemical sensing, and optoelectronic functional materials. However, conventional organic luminophores often suffer from aggregation-caused quenching (ACQ) in the solid state, which limits their luminescent performance. Recently, incorporating aggregation-induced emission (AIE) characteristics into HOFs has emerged as an effective strategy to overcome ACQ. This review summarizes recent advances in AIE-active fluorescent and phosphorescent HOFs, focusing on their structural design, mechanisms, and applications, and briefly discusses current challenges and future perspectives.

Key words: Aggregation-induced emission; Hydrogen-bonded organic frameworks, Fluorescence, Phosphorescence

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