高等学校化学学报

高等学校化学学报

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荧光超分子聚合物网络

任奥成1,李青云1,吉晓帆2   

  1. 1. 温州医科大学药学院 2. 华中科技大学化学与化工学院
  • 收稿日期:2025-12-22 修回日期:2026-01-20 网络首发:2026-02-04 发布日期:2026-02-04
  • 通讯作者: 吉晓帆 E-mail:xiaofanji@hust.edu.cn
  • 基金资助:
    华中科技大学“交叉研究支持计划”(批准号: 2025JCYJ055)、国家自然科学基金(批准号: 52473006; 22505183)、温州医科大学启动经费(批准号: 89225003)资助

Fluorescent Supramolecular Polymer Networks

REN Aocheng1, LI Qingyu1*, JI Xiaofan2*   

  1. 1. Wenzhou Medical University, School of Pharmaceutical Sciences 2. Huazhong University of Science and Technology, School of Chemistry and Chemical Engineering
  • Received:2025-12-22 Revised:2026-01-20 Online First:2026-02-04 Published:2026-02-04
  • Supported by:
    Supported by the Interdisciplinary Research Program of Huazhong University of Science and Technology, China(No.2025JCYJ055), the National Natural Science Foundation of China(Nos.52473006, 22505183), the Start-up Funding from the Wenzhou Medical University. China(No.89225003)

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摘要： 超分子聚合物网络（SPNs）是一类通过动态可逆的非共价相互作用将聚合物交联形成的功能体系，其独特结构推动了多种功能材料的发展。作为其中重要的分支，荧光超分子聚合物网络（FSPNs）通过巧妙结合非共价相互作用的动态性与荧光团丰富的光物理性质，显著拓展了聚合物材料的种类与功能维度，在信息存储材料、化学传感、光电功能材料等领域展现出广阔的应用前景。因此，本文依据非共价相互作用类型对近五年FSPNs的研究进展进行分类评述，并展望其未来发展方向。本综述旨在系统梳理该领域的制备策略与应用现状，以期为深入理解FSPNs提供参考，并对构建先进荧光材料与多功能聚合物材料的设计提供有益借鉴。

关键词: 荧光, 超分子聚合物网络, 聚集诱导发光, 组装

Abstract: Supramolecular polymer networks (SPNs) are a class of functional systems formed by cross-linking polymers through dynamic and reversible non-covalent interactions. Their unique structures have driven the development of various functional materials. As an important branch, fluorescent supramolecular polymer networks (FSPNs) significantly expand the variety and functional dimensions of polymer materials by ingeniously combining the dynamic nature of non-covalent interactions with the rich photophysical properties of fluorophores. These systems exhibit broad application prospects in fields such as information storage materials, chemical sensing, and optoelectronic functional materials. Herein, this review summarized the research progress of FSPNs in the past five years, taking the types of non-covalent interactions as the main thread, and looks forward to their future development directions. This review aims to systematically summarize the preparation strategies and application status in this field, providing references for an in-depth understanding of FSPNs and offering valuable insights for the design of advanced fluorescent materials and multifunctional polymer materials.

Key words: Fluorescence, Supramolecular polymer network, Aggregation-induced emission, Assembly

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