Bi25FeO40/α-Fe2O3复合纳米颗粒光催化剂的制备与性能

doi:10.7503/cjcu20170425

高等学校化学学报 ›› 2018, Vol. 39 ›› Issue (4): 629.doi: 10.7503/cjcu20170425

• 研究论文: 无机化学 • 上一篇下一篇

Bi₂₅FeO₄₀/α-Fe₂O₃复合纳米颗粒光催化剂的制备与性能

丛日敏¹(), 于怀清¹, 罗运军², 李蛟¹, 王卫伟¹, 李秋红¹, 孙武珠¹, 司维蒙¹, 张华¹

1. 山东理工大学材料科学与工程学院, 淄博 255049
2. 北京理工大学材料科学与工程学院, 北京 100081

收稿日期:2017-07-03 出版日期:2018-04-10 发布日期:2018-03-21
作者简介:联系人简介: 丛日敏, 女, 博士, 副教授, 主要从事新型功能材料方面的研究. E-mail:congrimin0219@163.com
基金资助:
山东省高等学校科技计划项目(批准号: J11LD12)、山东省自然科学基金(批准号: ZR2011BL006, ZR2010BM011, ZR2015BM02)和山东理工大学青年教师发展支持计划项目资助

Synthesis and Properties of Bi₂₅FeO₄₀/α-Fe₂O₃ Composite Nanoparticle Photocatalysts^†

CONG Rimin^1,^*(), YU Huaiqing¹, LUO Yunjun², LI Jiao¹, WANG Weiwei¹, LI Qiuhong¹, SUN Wuzhu¹, SI Weimeng¹, ZHANG Hua¹

1. School of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, China
2. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

Received:2017-07-03 Online:2018-04-10 Published:2018-03-21
Contact: CONG Rimin E-mail:congrimin0219@163.com
Supported by:
† Supported by the Project of Shandong Province Higher Educational Science and Technology Program, China(No.J11LD12), the Natural Science Foundation of Shandong Province, China(Nos.ZR2011BL006, ZR2010BM011, ZR2015BM02) and the Young Teachers Program of Shandong University of Technology, China

摘要/Abstract

摘要：

采用溶剂热法, 以聚酰胺-胺(PAMAM)树形分子为稳定剂, 分别制备了Bi₂₅FeO₄₀和Bi₂₅FeO₄₀/α-Fe₂O₃复合纳米颗粒, 并利用X射线衍射仪(XRD)、高分辨透射电镜(HRTEM)、 X射线光电子能谱仪(XPS)、紫外-可见吸收光谱仪(UV-Vis)、比表面积和孔径分析仪(BET)和超导量子干涉磁强计等对其结构和性能进行了表征. 结果表明, 2种颗粒均为球形, 尺寸均匀, 粒径小于10 nm. 当原料中Bi³⁺/Fe³⁺摩尔比为25:1时, 产物为Bi₂₅FeO₄₀纳米颗粒; Bi³⁺/Fe³⁺摩尔比为1:1时, 产物为Bi₂₅FeO₄₀/α-Fe₂O₃复合纳米颗粒. 与Bi₂₅FeO₄₀纳米颗粒相比, Bi₂₅FeO₄₀/α-Fe₂O₃复合纳米颗粒的带隙变窄, 对可见光吸收范围变宽, 饱和磁化强度和光催化活性明显增强. 这是由于复合颗粒中的α-Fe₂O₃具有超顺磁性, 且两相界面存在的异质结构有利于光生载流子的分离和迁移, 提高催化活性. 2种纳米颗粒均可磁性回收, 重复使用3次后催化活性下降较小.

关键词: Bi₂₅FeO₄0, α-Fe₂O₃, 复合纳米颗粒, 磁性, 光催化剂

Abstract:

Pure Bi₂₅FeO₄₀ nanoparticles and Bi₂₅FeO₄₀/α-Fe₂O₃ composite nanoparticles were synthsized through solvothermal porcess by using polyamidoamine(PAMAM) dendrimer stabilizer with a Bi³⁺/Fe³⁺ molar ratio of 25:1 and 1:1 in the reaction system, respectively. The structure, morphology and properties of the samples were characterized by X-ray diffraction(XRD), high resolution transmission electron microscopy(HRTEM), X-ray photoelectron spectroscopy(XPS), ultraviolet-visible spectroscopy(UV-Vis), Brunauer-Emmett-Teller(BET) surface area analysis and magnetic hysteresis loops measurenent. The results show that these particles are uniform balls with the diameter less than 10 nm. Compared with pure Bi₂₅FeO₄₀ nanoparticles, Bi₂₅FeO₄₀/α-Fe₂O₃ composite nanoparticles have smaller band gap, broader visible light absorption range, and significantly greater saturation magnetization and photocatalytic activity. These excellent properties of Bi₂₅FeO₄₀/α-Fe₂O₃ composite nanoparticles come from the superparamagnetic α-Fe₂O₃component, and the heterogeneous structure of the phase boundary which promotes the efficient separation and migration of photogenerated carriers at the junction interfaces. These nanoparticles could be recycled in external magnetic field, and the catalytic activity decreased slightly after being reused for 3 times.

Key words: Bi₂₅FeO₄0, α-Fe₂O₃, Composite nanoparticles, Magnetic property, Photocatalyst

中图分类号:

O614

TrendMD:

丛日敏, 于怀清, 罗运军, 李蛟, 王卫伟, 李秋红, 孙武珠, 司维蒙, 张华. Bi₂₅FeO₄₀/α-Fe₂O₃复合纳米颗粒光催化剂的制备与性能. 高等学校化学学报, 2018, 39(4): 629.

CONG Rimin, YU Huaiqing, LUO Yunjun, LI Jiao, WANG Weiwei, LI Qiuhong, SUN Wuzhu, SI Weimeng, ZHANG Hua. Synthesis and Properties of Bi₂₅FeO₄₀/α-Fe₂O₃ Composite Nanoparticle Photocatalysts^†. Chem. J. Chinese Universities, 2018, 39(4): 629.

图/表 8

Fig.1 XRD patterns of S1(a), S2(b), S3(c) and S4(d)

Fig.2 HRTEM images of S1(A, B) and S2(C, D)

Fig.3 XPS survey(A) and high-resolution sepctra of Bi4f(B) and Fe2p(C) of S1(a) and S2(b)

Fig.4 UV-Vis absorption spectra of S1(a), S2(b) and S3(c)Inset shows the plots of (Ahν)2 as a function of photon energy hν at the absorption edges.

Fig.5 Room temperature hysteresis loops of S1(a) and S2(b)Inset shows the enlarged view of coordinate origin.

Fig.6 Degradation of MB without(a) and with S1(b) or S2(c) nanoparticles as photocatalysts

Fig.7 Schematic diagram of the energy band structure of S2

Table 1 Catalytic activity of nanoparticles recycled and reused for 3 times

Sample	Degradation rate of MB(%)
Sample	1st	2nd	3rd
Bi₂₅FeO₄₀	57.6	52.4	50.5
Bi₂₅FeO₄₀/α-Fe₂O₃	90.9	87.2	86.3

参考文献 32

[1]	Ortiz-Quinonez J. L., Diaz D., Zumeta-Dube I., Arriola-Santamaria H., Betancourt I., Santiago-Jacinto P., Nava-Etzana N., Inorg. Chem., 2013, 52, 10306-10317
[2]	Wang X., Zhang M., Tian P., Chin W. S., Zhang C. M., Appl. Surf. Sci., 2014, 321, 144-149
[3]	Chen Y., Wu Q., Zhao J., J. Alloy Compd., 2009, 487, 599-604
[4]	Shi X. X., Xiao R. J., Wang Z., Zhou J. P., Bian X. B., Chem. J. Chinese Universities, 2015, 36(12), 2364-2371
	(师旋旋, 肖瑞娟, 王振, 周剑平, 边小兵. 高等学校化学学报, 2015, 36(12), 2364-2371)
[5]	Huang F., Wang Z., Lu X., Zhang J., Min K., Lin W., Ti R., Xu T., He J., Yue C., Zhu J., Sci. Rep-UK, 2013, 3, 1-7
[6]	Hasana M, Islam M. F., Mahbub R, Hossain M. S., Hakim M. A., Mater. Res. Bull., 2016, 73, 179-186
[7]	Sosnowska I., Neumaier T. P., Steichele E., J. Phys. C, Solid State Phys., 2000, 15(23), 4835-4846
[8]	Wang Y., He R., Yang M., Wen T., Zhang H., Liang J., Lin Z., Wang Y., Li G., Lin J., Cryst. Eng. Comm., 2012, 14, 1063-1068
[9]	Goldman A. R., Fredricks J. L., Estroff L. A., J. Cryst. Growth, 2017, 468, 104-109
[10]	Oak J. J., Cho Y. J., Chun H. H., Park Y. H., Phys. Met. Metallogr., 2014, 115(13), 1342-1350
[11]	Zhang L., Zou Y., Song J., Pan H. L., Sheng S. D., Hou C. M., RSC Adv., 2016, 6(31), 26038-26044
[12]	Zang X. N., Sun H. J., China Ceramics, 2016, 52(9), 33-40
	(张小娜, 孙华君. 中国陶瓷, 2016, 52(9), 33-40)
[13]	Sun H. J., Liu Y., Zhang Y., Guo S. S., Lü L., Chen W., J. Founct. Mater., 2015, 46(4), 04016-04018
	(孙华君, 刘依, 张勇, 郭姗姗, 吕来, 陈文. 功能材料, 2015, 46(4), 04016-04018)
[14]	Lopes A. M. L., Araujoa J. P., Ferdov S., Dalton Trans., 2014, 43, 18010-18016
[15]	Ren L., Lu S. Y., Fang J. Z., Wu Y., Chen D. Z., Huang L. Y., Chen Y. F., Cheng C., Liang Y., Fang Z. Q., Catal. Today, 2017, 281, 656-661
[16]	Li P., Chen Q., Lin Y. Y., Chang G., He Y. B., J. Alloy Compd., 2016, 672, 497-504
[17]	Sun A., Chen H., Song C., Jiang F., Wang X., Fu Y., RSC Adv., 2013, 3, 4332-4340
[18]	Lv M., Yang H., Xu Y., Chen Q., Liu X., Wei F., J. Environ. Chem. Eng., 2015, 3, 1003-1008
[19]	Zhang L., Zhang X., Zou Y., Xu Y. H., Pan C. L., Hu J. S., Hou C. M., Cryst. Eng. Comm., 2015, 17, 6527-6537
[20]	Wu L., Dong C., Chen H., Yao J., Jiang C., Xue D., J. Am. Ceram. Soc., 2012, 95, 3922-3927
[21]	Koferstein R., Buttlar T., Ebbinghaus S. G., J. Solid State Chem., 2014, 217, 50-56
[22]	Cui Y.X., Optimum Process of Preparing PAMAM Dendrimer and Its Application in Organic-inorganic Hybrids, Beijing Institute of Technology, Beijing, 2003
	(崔艳霞. 聚酰胺-胺(PAMAM)树形分子的合成条件优化及其在有机-无机复合材料中的应用, 北京: 北京理工大学, 2003)
[23]	Cong R. M., Luo Y. J., Li G. P., Tan H. M., Chem. J. Chinese Universities, 2006, 27(5), 793-796
	(丛日敏, 罗运军, 李国平, 谭惠民. 高等学校化学学报, 2006, 27(5), 793-796)
[24]	Chen A. R., Xu L., Zhang X. J., Yang Z. M., Yang S. C., ACS Appl. Mater. Interfaces, 2016, 8, 33765-33774
[25]	Zhang Z., Lu J. P., Yun T., Zheng M. R., Pan J. S., Sow C. H., Tok E. S., J. Phys. Chem. C, 2013, 117, 1509-1517
[26]	Wang S., Chen D., Niu F., Zhang N., Qin L. S., Huang Y. X., J. Alloy Compd., 2016, 688, 399-406
[27]	Dai Y. R., Yin L. F., J. Alloy Compd., 2013, 563, 80-84
[28]	Tang B., Wang G. L., Zhuo L. H., Ge J., Cui L., J. Inorg. Chem., 2006, 45(13), 5196-5200
[29]	Zou Y., The Preparation and Capacity of Photocatalyst on the Basic of Bi25FeO40, Bi2WO6, Anhui University of Science and Technology School, Huainan, 2016
	(邹玥. 基于铁酸铋与钨酸铋的光催化剂的制备及其光催化性能的研究, 淮南: 安徽理工大学, 2016)
[30]	Pradhan G. K., Parida K. M., ACS Appl. Mater. Interfaces, 2011, 3(2), 317-323
[31]	Lassoued A., Dkhil B., Gadri A., Ammar S., Results Phy., 2017, 7, 3007-3015
[32]	Wu W., Zhang S., Xiao X., Zhou J., Ren F., Sun L., Jiang C., ACS Appl. Mater. Interfaces, 2012, 4(7), 3602-3609

Bi₂₅FeO₄₀/α-Fe₂O₃复合纳米颗粒光催化剂的制备与性能

Synthesis and Properties of Bi₂₅FeO₄₀/α-Fe₂O₃ Composite Nanoparticle Photocatalysts^†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 32

相关文章 15

编辑推荐

Metrics

本文评价

[1]	郭彪, 赵晨灿, 刘芯辛, 于洲, 周丽景, 袁宏明, 赵震. 表面水热碳层对磁性NiFe₂O₄八面体光催化活性的影响[J]. 高等学校化学学报, 2022, 43(11): 20220472.
[2]	杨晓梅, 吴强, 郭茹, 叶凯波, 薛屏, 王晓中, 赖小勇 . 超薄骨架有序介孔CdS/NiS的制备及光催化产氢性能[J]. 高等学校化学学报, 2021, 42(5): 1581.
[3]	郑海娇, 姜丽艳, 贾琼. 精氨酸功能化磁性纳米材料的制备及在磷酸化肽富集中的应用[J]. 高等学校化学学报, 2021, 42(3): 717.
[4]	阮泽宇, 杜杉楠, 黄国璋, 童明良, 刘俊良. 原位合成手性镍配合物中的阻转异构及磁性研究[J]. 高等学校化学学报, 2021, 42(3): 709.
[5]	李菲, 李小轩, 李一峻, 何锡文, 陈朗星, 张玉奎. 表面定向磁性印迹聚合物的制备及对槲皮素的选择性识别[J]. 高等学校化学学报, 2021, 42(12): 3606.
[6]	孙启睿, 赵楠, 刘树威, 辛华, 张皓, 张乐宁. 用于磁性靶向治疗肺纤维化的聚多巴胺包覆的Fe₃O₄/甲强龙/环磷酰胺复合超粒子[J]. 高等学校化学学报, 2021, 42(10): 3225.
[7]	张作然, 张利, 张志凌. 基于侧向磁泳的微流控芯片对两种磁性纳米球的同时分选[J]. 高等学校化学学报, 2020, 41(6): 1243.
[8]	赵孟欣, 孟哲, 李和平, 马宗琴, 詹海鹃, 刘万毅. 氧化石墨烯调控钼酸铋在可见光下选择性光催化降解环境水中的抗生素[J]. 高等学校化学学报, 2020, 41(11): 2479.
[9]	王晓慧, 王可心, 刘俊平, 洪霞. 介孔结构增强的Fe₃O₄超粒子@介孔SiO₂的光热性能[J]. 高等学校化学学报, 2019, 40(8): 1586.
[10]	李泽, 王建江, 高海涛, 赵芳. 多孔羰基铁/CoFe₂O₄/聚苯胺复合材料的制备及吸波机理[J]. 高等学校化学学报, 2019, 40(8): 1784.
[11]	李岚, 钱勇, 杨东杰, 邱学青. 纳米木质素/二氧化硅基微胶囊的制备及在自愈合涂层中的应用[J]. 高等学校化学学报, 2019, 40(6): 1293.
[12]	吴姗姗, 魏缠玲, 赵丽娟, 田央, 王霞, 龚波林. 新型磁性限进分子印迹复合材料的制备及富集性能[J]. 高等学校化学学报, 2019, 40(6): 1150.
[13]	何鹏琛, 周健, 周阿武, 豆义波, 李建荣. MOFs基材料在光催化CO₂还原中的应用[J]. 高等学校化学学报, 2019, 40(5): 855.
[14]	段秉怡, 王宇, 郭宁宁, 王润伟, 张宗弢, 裘式纶. 蛋黄-壳结构Fe₃O₄@SiO₂@PMO磁性微球的制备及对漆酶的固定化[J]. 高等学校化学学报, 2019, 40(2): 210.
[15]	石宝珍,李杉,王佃鹏,周云志,孙锦玉. Co(Ⅱ)-Zn(Ⅱ)掺杂配位聚合物的合成及物理性能[J]. 高等学校化学学报, 2019, 40(12): 2443.