关键词: 氧化铝, 氧化铝, 载体, 载体, 胶溶, 胶溶, 结构, 结构, 织构, 织构

Abstract: Alumina prepared by peptizing method with a high specific surface area, moderate pore structure and pore size distribution was studied. Furthermore, the effects of additives La and PEG on thermal stability, particle size, structure and texture of alumina were investigated. The results of characterization of BET and XRD show that the addition of La greatly inhibits the loss of specific surface area and α phase transformation of alumina under the hydrothermal and high temperature conditions. At the same time, PEG as an additive can apparently increase pore volume and pore diameter of alumina. The more the La and PEG content is, the larger the surface area, pore volume and average diameter of alumina are. However, when the quantity ratio of La₂O₃ to Al₂O₃ or PEG to Al₂O₃ is excessive, the negative action of La and PEG are stronger. When the quantity ratio of La₂O₃/Al₂O₃ is 2.5%—3.0%, thermal stability of γ-Al₂O₃ is the best and specific surface area of alumina is more than 140 m²/g after hydro thermally being aged at 1000 ℃ for 5 h. Though PEG plays a good role on making pore and aggregation when the value of quantity ratio of PEG/Al₂O₃ is 80%, the thermal stability of alumina is worse and specific surface area is only 136.4 m²/g, pore volume is 0.41 mL/g and pore diameter is 9.38 nm under the same aging condition. Fortunately, after hydro thermally being aged at 1000 ℃ for 5 h, the alumina containing 2.5%La₂O₃ and 80%PEG of quantity of alumina has the best thermal stabilization and the largest specific surface area, pore volume and pore diameter that are 156.2 m²/g, 0.57 mL/g and 11 nm, respectively.

Key words: Alumina, Alumina, Support, Support, Peptization, Peptization, Structure, Structure, Texture, Texture