高等学校化学学报

高等学校化学学报 ›› 2006, Vol. 27 ›› Issue (4): 745.

• 研究论文 • 上一篇    下一篇

左旋聚乳酸的结晶行为研究

何勇1, 高兆芬2, 辛燕1, 于 瀛1, 李速明1, 范仲勇1   

  1. 1. 复旦大学材料科学系, 上海  200433; 2. 上饶师范学院化学系, 上饶  334000
  • 收稿日期:2005-05-19 出版日期:2006-04-10 发布日期:2006-04-10
  • 通讯作者: 范仲勇(1962年出生), 男, 博士, 教授. 主要从事材料结构与性能及高分子结晶研究. E-mail: zyfan@fudan.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 20474013)资助

Crystallization Behavior of Poly(L-lactide)

HE Yong1, GAO Zhao-Fen2, XIN Yan1, YU Ying1, LI Su-Ming1, FAN Zhong-Yong1*   

  1. 1. Department of Materials Science, Fudan University, Shanghai 200433, China;
    2.  Department of Chemistry, Shangrao Normal Institute, Shangrao 334000, China
  • Received:2005-05-19 Online:2006-04-10 Published:2006-04-10
  • Contact: FAN Zhong-Yong,E-mail: zyfan@fudan.edu.cn

PDF (PC)

被引次数

44

摘要：

用DSC, WAXD和POM对Zn催化剂制备的左旋聚乳酸(PLLA)的熔体结晶行为进行了研究. 在95~125 ℃范围内, PLLA熔体结晶生成厚度约(14±1) nm的片晶, 该片晶不易发生熔体等温增厚. 对实验数据分别用Avrami方程和Arrhenius方程进行了计算, Avrami指数n=3±0.3, 表明PLLA以球晶形式生长, 其最大结晶速率温度为(105.0±0.5) ℃, t1/2约为5.2 min. 利用Lauritzen-Hoffmann（LH）理论对PLLA结晶机理进行了分析, 发现PLLA结晶的Regime Ⅱ和Regime Ⅲ的转变温度为107 ℃. Kg(Ⅱ)和Kg(Ⅲ)分别为4.57×105 K2和1.115×106 K2, 且Kg(Ⅲ)/Kg(Ⅱ)=2.4, 与LH理论值一致.

关键词: 左旋聚乳酸; 熔体结晶; 结晶行为

Abstract:

Melt-crystallization behavior of poly(L-lactide) (PLLA) synthesized by Zn metal was investigated by using DSC, WAXD and POM. The crystallization behavior from the melt was investigated in the range from 368 to 398 K. The thicknesses of lamellae was (14±1) nm, and the thickening effect was not obvious. The results were treated with Avirami equation and Arrhenius equation. Avrami index n  is 3±0.3 which means that spherulites morphology of PLLA crystals formed in the temperature range; A maximum in the crystallization kinetics was observed around 378 K; half time of crystallization at 378 K was about 5.2 min. Lauritzen-Hoffmann(LH) theory was used to investigate the crystallization mechanism of PLLA, presenting the transition from regime Ⅱ to regime Ⅲ is approximately 380 K. The values of Kg(Ⅱ)  and Kg(Ⅲ) were 4.57×105 K2 or 1.115×106K2, respectively. And Kg(Ⅲ)/Kg(Ⅱ)=2.44, which accords with the value forecasted by LH theory.

Key words: Poly(L-lactide); Melt crystallization; Crystallization behavior

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