高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (11): 2567-2572.doi: 10.7503/cjcu20120186

• 高分子化学 • 上一篇    下一篇

具有温度响应壳层的金纳米粒子的制备

王大鹏, 杨木泉, 董志鑫, 薄淑琴, 姬相玲   

  1. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:2012-03-05 出版日期:2012-11-10 发布日期:2012-10-15
  • 通讯作者: 姬相玲,女,博士,研究员,主要从事高分子溶液、链结构及多孔高分子的研究.E-mail:xlji@ciac.jl.cn E-mail:xlji@ciac.jl.cn
  • 基金资助:

    国家自然科学基金(批准号: 50921062)资助.

Preparation of Gold Nanoparticles with Temperature Responsive Shell

WANG Da-Peng, YANG Mu-Quan, DONG Zhi-Xin, BO Shu-Qin, JI Xiang-Ling   

  1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  • Received:2012-03-05 Online:2012-11-10 Published:2012-10-15
  • Contact: 相玲 姬 E-mail:xlji@ciac.jl.cn

摘要:

利用可逆-加成断裂链转移聚合得到全亲水性的嵌段共聚物(PEO-b-PNIPAM), 通过"grafting to"使其接枝到金纳米粒子表面. 通过透射电子显微镜、 紫外-可见吸收光谱、 能谱分析及动态光散射研究了杂化的金纳米粒子的壳层结构及温度响应行为. 实验结果表明, 得到核壳结构的金纳米粒子, 同时其壳层具有温度响应行为. 随着温度的升高, 其流体力学半径略有减小. 在整个升温过程中, 由于外层PEO链段的抑制作用, 没有发生粒子间的聚集.

关键词: 可逆-加成断裂链转移聚合, 配体交换, 核壳结构的金纳米粒子, 温度响应性

Abstract:

Double-hydrophilic block polymer poly(ethylene oxide)-b-poly(N-isopropylacrylamide)(PEO-b-PNIPAM) was synthesized by reversible addition-fragmentation chain transfer polymerization using PEO based macro RAFT(reversible addition-fragmentation chain transfer) agent, and the block polymer was further grafted to the surface of gold nanoparticles by "grafting to" approach. The structure and temperature responsive behavior of obtained hydride gold nanoparticles were characterized by transmission electron microscopy (TEM), UV-Vis transmission, energy dispersed X-ray spectrometer and dynamic light scattering(DLS). The results show that core/shell gold nanoparticles were prepared. The average hydrodynamic radius(Rh) of core/shell gold nanoparticles slightly decreased with the temperature increasing. And there is no aggregation between core/shell gold nanoparticles during heating process due to the inhibition effects of PEO corona.

Key words: Reversible addition-fragmentation chain transfer polymerization, Ligand exchange, Core/shell gold nanoparticles, Temperature responsive behavior

中图分类号: