高等学校化学学报

高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (10): 2351.doi: 10.7503/cjcu20111022

• 高分子化学 • 上一篇    下一篇

两种偶氮分子玻璃材料的光致取向特性

王艳伟, 和亚宁, 王晓工   

  1. 清华大学化工系高分子研究所, 教育部先进材料重点实验室, 北京 100084
  • 收稿日期:2011-11-03 出版日期:2012-10-10 发布日期:2012-09-12
  • 通讯作者: 王晓工, 男, 教授, 博士生导师, 主要从事功能高分子研究. E-mail: wxg-dce@mail.tsinghua.edu.cn E-mail:wxg-dce@mail.tsinghua.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 91027024, 51061130556)资助.

Photoinduced Orientation of Two Dendritic Azo Amorphous Molecular Materials

WANG Yan-Wei, HE Ya-Ning, WANG Xiao-Gong   

  1. Laboratory of Advanced Materials, Ministry of Education, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  • Received:2011-11-03 Online:2012-10-10 Published:2012-09-12

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摘要：

利用光诱导双折射和偏振红外光谱法研究了2种无定形树枝状偶氮分子材料G1-AZ-CN和G2-AZ-CN的光致取向行为, 对其偶氮生色团及非光响应性星形核的光致取向速度、 取向松弛速度和饱和取向程度进行了系统研究. 结果表明, G2-AZ-CN中偶氮生色团和星形核的光致取向速度快于G1-AZ-CN, 但其取向松弛速度慢于G1-AZ-CN, 这与G2-AZ-CN具有更高的偶氮生色团密度有关. G1-AZ-CN具有较高的饱和取向程度及较好的取向稳定性. 与具有相同类型偶氮生色团的偶氮聚合物BP-AZ-CN相比, G1-AZ-CN和G2-AZ-CN中偶氮生色团表现出较慢的取向速度. 其取向行为与其特殊的星形分子结构有关.

关键词: 光致取向, 树枝状偶氮分子, 无定形分子材料, 偏振红外光谱

Abstract:

The orientation behavior of two dendritic azo compounds, G1-AZ-CN and G2-AZ-CN were studied by photoinduced birefringence method and polarized infrared spectroscopy. The chemical structure difference between G1-AZ-CN and G2-AZ-CN is the density of azo chromophore. The orientation rate, relaxation rate and saturated orientation level of dendritic azo compound are related to its special chemical structures. Both azo chromophore and dendritic core of G2-AZ-CN show faster orientation rate but slower relaxation rate than that of G1-AZ-CN, which could be attributed to the higher azo chromophore density of G2-AZ-CN. G1-AZ-CN reserved higher photoinduced orientation after relaxation than G2-AZ-CN. The saturated orientation level of both azo chromophore and dendritic core of G1-AZ-CN is higher than that of G2-AZ-CN, in which the special chemical structure can play a critical role.

Key words: Photo-induced orientation, Dendritic azo compound, Amorphous molecular material, Polarized FTIR spectrum

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