高等学校化学学报

高等学校化学学报 ›› 2005, Vol. 26 ›› Issue (1): 19.

• 研究简报 • 上一篇    下一篇

二维网状银配合物的合成、结构与性质研究

朱惠芳, 樊健, 孙为银   

  1. 南京大学配位化学研究所, 配位化学国家重点实验室, 南京 210093
  • 收稿日期:2004-06-08 出版日期:2005-01-10 发布日期:2005-01-10
  • 通讯作者: 孙为银(1964年出生),男,教授,主要从事超分子化学及生物无机化学研究.E-mail:sunwy@nju.edu.cn E-mail:sunwy@nju.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:20231020)资助

Synthesis, Structure and Property of a 2D Network of Silver Complex

ZHU Hui-Fang, FAN Jian, SUN Wei-Yin   

  1. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, China
  • Received:2004-06-08 Online:2005-01-10 Published:2005-01-10

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被引次数

16

关键词: 银(Ⅰ)配合物, 叠氮根, 含咪唑基配体, C_H&hellip, &pi, 作用

Abstract: A new coordination complex, [Ag(IIMB)N3], was prepared by self-assembly of asymmetric ligand 1-(1-imidazolyl)-4-(imidazol-1-ylmethyl)benzene(IIMB) with [Ag(NH3)2]N3. The crystal structural analysis indicates that the structure of the complex contains fifty-two-membered macrometallacyclic rings, and the complex crystallizes in monoclinic system, space group of P21/c with a=0.739 8(1) nm, b=1.045 1(1) nm, c=1.812 4(2)nm, β=91.65(1)°, V=1.400 7(3) nm3, Z=4, Dc=1.774 g/cm3, F(000)=744, R=0.050 5, wR=0.084 0. It is notable that the azide ion bridges two silver(Ⅰ) atoms in end-on fashion.

Key words: Silver(Ⅰ) complex, Azide, Ligand containing imidazolyl, C_H…%π% interaction

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