高等学校化学学报

高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (5): 817.

• 研究简报 • 上一篇    下一篇

以二茂铁二羧酸为配体的锌配位聚合物[Zn(Py)2L]n的合成与晶体结构

冷思伟, 吴刚, 辛明红, 唐璐璐, 朱广山, 范勇, 史苏华   

  1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春130023
  • 收稿日期:2003-04-21 出版日期:2004-05-24 发布日期:2004-05-24
  • 通讯作者: 史苏华(1958年出生),女,博士研究生,副教授,从事功能无机化合物研究.E-mail:shisuhua2003@yahoo.com.cn E-mail:shisuhua2003@yahoo.com.cn
  • 基金资助:

    吉林大学无机合成与制备化学国家重点实验室资助

Synthesis and Crystal Structure of Zinc Coordination Polymer with Ferrocenedicarboxylic Acid as Ligand

LENG Si-Wei, WU Gang, XIN Ming-Hong, TANG Lu-Lu, ZHU Guang-Shan, FAN Yong, SHI Su-Hua   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, China
  • Received:2003-04-21 Online:2004-05-24 Published:2004-05-24

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关键词: 配位聚合物, 二茂铁二羧酸, 晶体结构

Abstract: The title compound [Zn(Py)2L]n(L=1,2′-ferrocenedicarboxylate) was synthesized under mild conditions and its crystal structure was characterized. It crystallizes in a monoclinic system, space group C2/c with the cell parameters a=1.683 0(5) nm, b=1.380 4(3) nm, c=1.746 2(3) nm, β=108.78(2)°, V=3.840 8(15) nm3, Z=8, Mr=485.52, T=293(2) K, Dc=3.359 Mg/m3, μ= 4.073 mm-1, F(000)=3 872, R1=0.040 1, wR2=0.113 2. The compound exhibits an unusual one-dimensional chain consisting of two zigzag chains.

Key words: Coordination Polymer, Ferrocenedicarboxylic Acid, Crystal structure

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