高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (6): 993.

• 研究简报 • 上一篇    

一种带有芳基双亲双官能度引发剂的合成

周广昌1, 黄鹏程2, 朱鹤孙3   

  1. 1. 北京理工大学化工与材料学院, 北京 100081;
    2. 北京航空航天大学材料科学与工程系, 北京 100083;
    3. 京理工大学材料科学研究中心, 北京 100081
  • 收稿日期:1998-06-29 出版日期:1999-06-24 发布日期:1999-06-24
  • 通讯作者: 黄鹏程
  • 作者简介:周广昌,男,32岁,博士,高级工程师.
  • 基金资助:

    国家自然科学基金(批准号:29374154)资助课题

Synthesis of an Amphiphilic BifunctionaL INitiatorwith an Aromatic Group

ZHOU Guang-Chang1, HUANG Peng-Cheng2, ZHU He-Sun3   

  1. 1. College of Chemical Engineering and Materials Science, Beijing, Institute of Technology, Beijing, 100081;
    2. Research Center of Materials Science, Beijing, Institute of Technology, Beijing, 100081;
    3. Department of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing, 100083
  • Received:1998-06-29 Online:1999-06-24 Published:1999-06-24

PDF (PC)

被引次数

5

摘要： 双亲聚合物已广泛地应用于许多领域[1],但其制备困难[2~4].

关键词: 双亲双官能度引发剂, 自由基界面共聚合, 对甲苯甲酰(3-羧丙酰)癸二酰二过氧化物

Abstract: An amphiphilic bifunctionaLINitiator with an aromatic group, which is used in free radicaLINterfacial copolymerization, p-toluoyl(3-carboxypropionyl)sebacoyl diperoxide(MBSD), was synthesized by the successive condensation of sebacoyl chloride with p-methylperoxybenzoic acid and monoperoxysuccinic acid under the catalysis of pyridine and further characterized by IR, 1HNMR, MS, elemental analysis and the analysis of peroxide oxygen content.

Key words: Amphiphilic bifunctional initiator, Free radical interfacial copolymerization, p-Toluoyl(3-carboxypropionyl)sebacoyl diperoxide

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