高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (8): 1208.

• 研究简报 • 上一篇    下一篇

三元体系Zn(ClO4)2-BAPHDCA-H2O(30℃)的相平衡研究及Zn(BAPHDCA)(ClO4)2·2H2O的合成与表征

崔斌, 唐宗薰, 郭志箴, 陈开勋   

  1. 西北大学化学系, 西安, 710069
  • 收稿日期:1997-06-05 出版日期:1998-08-24 发布日期:1998-08-24
  • 通讯作者: 崔斌,男,29岁,硕士,讲师.
  • 作者简介:崔斌,男,29岁,硕士,讲师.
  • 基金资助:

    国家自然科学基金(批准号:840109)及北京大学稀土材料化学及应用国家重点实验室资助课题.

A Study of the Ternary System of Zn(ClO4)2-BAPHDCA-H2O at 30℃ and the Preparation and Characterization of the Zn(BAPHDCA)(ClO4)2·2H2O

CUI Bin, TANG Zong-Xun, GUO Zhi-Zhen, CHEN Kai-Xun   

  1. Department of Chemistry, Northwest University, Xi′an, 710069
  • Received:1997-06-05 Online:1998-08-24 Published:1998-08-24

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摘要： 安替比林(AP)及其4位取代衍生物与各种稀土盐及过渡金属盐之间的化学行为已有广泛的研究.为了进一步考察安替比林类衍生物与过渡金属盐形成双核或多核化合物的可能性.

关键词: 相平衡, 三元体系, N, N&prime, －二安替比林－1, 6－己二酰胺, 高氯酸锌

Abstract: The solubilities and the refractive indexes of the saturated solutions of the titled system at 30 ℃ have been studied and the corresponding equilibrium diagram and refractive index diagram were constructed, both solubility curves and refractive index curves of the system consist of three branches, corresponding to BAPHDCA, Zn(BAPHDCA)(ClO4)2·2H2O and Zn(ClO4)2·6H2O, respectively. The Zn(BAPHDCA)(ClO4)2·2H2O is a new compound, which was characterized by chemical and elemental analysis, IRspectra and thermoanalysis.

Key words: Phase equilibrium, Ternary system, N,N′-Bis(antipyrine-4′-yl)-hexanedicarboxamide, Perchlorate zinc

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