高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (5): 665.

• 论文 •    下一篇

含氮Ylide对C60的1,3-偶极环加成反应法合成含吡咯环C60衍生物

周德建1, 赵一雷1, 甘良兵1, 骆初平1, 黄春辉1, 吕木坚2, 潘景歧2, 武轶3   

  1. 1. 北京大学稀土材料化学与应用国家重点实验室, 北京, 100871;
    2. 北京大学化学与分子工程学院, 北京, 100871;
    3. 北京微量化学研究所, 北京, 100091
  • 收稿日期:1996-05-23 出版日期:1997-05-24 发布日期:1997-05-24
  • 通讯作者: 甘良兵
  • 作者简介:周德建,男,28岁,博士.
  • 基金资助:

    国家攀登计划资助;国家自然科学基金;国家教育委员会优秀年轻教师基金

Synthesis of C60-Pyrrolidine Derivatives by 1,3-Dipolar Cycloaddition of Azomethine Ylides to C60

ZHOU De-Jian1, ZHAO Yi-Lei1, GAN Liang-Bing1, LUO Chu-Ping1, HUANG Chun-Hui1, LU Mu-Jian2, PAN Jinn-Qi2, WU Yi3   

  1. 1. State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871;
    2. College of Chemistry and Molecular, Engineering Peking University, Beijing, 100871;
    3. Beijing In.situte of Microchemistry, Beijing, 100091
  • Received:1996-05-23 Online:1997-05-24 Published:1997-05-24

摘要: 利用肌氨酸与对位含不同取代基的苯甲醛、共轭烯烃醛类及酮类反应生成的含氮Ylide对C60的加成反应,合成并分离、纯化制得了一系列含不同取代基的C60吡咯环纯衍生物,并用1HNMR、13CNMR、FDMS、FT-IR、UV-Vis等光谱手段确定了它们的分子结构.

关键词: C60吡咯环衍生物, 肌氨酸, 含氮Ylide, 1, 3-偶极环加成

Abstract: Aseries of different substituted azomethine Ylides were prepared through the reaction between sarcosine and different substituted benzoaldehydes, conjugated aldehydes and ketones.Further 1, 3-dipolar cycloaddition of these azomethine Ylides to C60 give rise to a series of new C60-pyrrolidine derivatives.The molecular structures of these compounds were ldent1fied and characterized by 1HNMR, 13CNMR, FDMS, FT-IRand UV-Vis spectro-scopies.

Key words: C60-Pyrrolidine derivative, Sarcosine, Azomethine ylides, 1,3-Dipolar cycloaddition

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