高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (8): 1161.

• 论文 •    下一篇

Eu2+和Mn2+在SrMgP2O7中的光致发光及其能量传递

姚光庆, 张亮, 苏勉曾   

  1. 北京大学化学系, 北京, 100871
  • 出版日期:1995-08-24 发布日期:1995-08-24
  • 基金资助:

    国家自然科学基金;国家重大基础研究项目

Luminescence of Eu2+and Mn2+and Their Energy Transfer in SrMgP2O7

YAO Guang-Qing, ZHANG Liang, SU Mian-Zeng   

  1. Department of Chemistry, Peking University, Beijing, 100871
  • Online:1995-08-24 Published:1995-08-24

摘要: 研究了Eu2+、Mn2+共激活的SrMgP2O7的发光性质、浓度与荧光性质的关系。Eu2+和Mn2+的发射光谱分别在400nm及670nm附近,它们是Eu2+的5d-4f跃迁和Mn2+4T1(4G)-6A1g(6S)跃迁发射,实验结果表明:Eu2+对Mn2+的荧光发射有较强的敏化作用,Mn2+对Eu2+的荧光寿命和强度也有显著影响。

关键词: 光致发光, 荧光寿命, 能量传递

Abstract: The fluorescence of Eu2+and Mn2+coactivated SrMgP2O7was reported.The emission bands of Eu2+and Mn2+peaking at 400 nm and 670 nm were originated from 5d-4f transition of Eu2+and 4T1(4G)-6Alg(6S) transition of Mn2+,respectively. The dependence of Eu2+and Mn2+luminescence properties on their concentration was investigated.The emission of Mn2+is sensitized by Eu2+and the fluorescence lifetime of Eu 2+is affected by Mn2+.The experimental results indicate that there exists an effective energy transfer from Eu2+to Mn2+in SrMgP2O7host.This energy transfer is due to the electric dipole-quadripole interaction of the resonance transfer.

Key words: Luminescence, Fluorescence lifetime, Energy transfer

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