高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (2): 265.

• 研究论文 • 上一篇    下一篇

Li/SOCl2电池的拉曼光谱电化学研究

钟发平1, 杨汉西1, 查全性1, 盛蓉生2, 徐知三2   

  1. 1. 武汉大学化学系, 武汉 430072;
    2. 武汉大学分析测试中心
  • 收稿日期:1992-02-21 修回日期:1992-11-09 出版日期:1993-02-24 发布日期:1993-02-24
  • 通讯作者: 钟发平

The Raman Spectroelectrochemical Research for Li/SOCl2 Cell

ZHONG Fa-Ping1, YANG Han-Xi1, ZHA Quan-Xing1, SHENG Rong-Sheng2, XU Zhi-San2   

  1. 1. Department of Chemistry, Wuhan University, Wuhan, 430072;
    2. Analytical Center, Wuhan University, Wuhan
  • Received:1992-02-21 Revised:1992-11-09 Online:1993-02-24 Published:1993-02-24

关键词: 锂电池, 拉曼光谱, 电化学

Abstract: Amicro-Raman electrochemical cell was designed for in-situ study of the electroreduction of SOCl2 .The results suggest that S2Cl2 is the mediate product during the reducing of SOCl2 on carbon electrode.With the help of cyclic voltammetry, a reasonable mechanism of SOCl2 reducing on carbon electrode was derived.

Key words: Li battery, Raman spectrum, Electrochemistry

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