高等学校化学学报

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (9): 1161.

• 论文 • 上一篇    下一篇

1,10-菲啰啉-1-氧化物及乙酸与稀土的双核配合物

刘伟生, 谭民裕   

  1. 兰州大学化学系, 兰州, 730000
  • 收稿日期:1991-09-19 修回日期:1992-04-12 出版日期:1992-09-24 发布日期:1992-09-24
  • 通讯作者: 谭民裕
  • 基金资助:

    国家自然科学基金

Binuclear Complexes of Rare Earth with 1,10-Phenanthroline-N-oxide and Acetic Acid

LIU Wei-Sheng, TAN Min-Yu   

  1. Department of Chemistry, Lanzhou University, Lanzhou, 730000
  • Received:1991-09-19 Revised:1992-04-12 Online:1992-09-24 Published:1992-09-24

PDF (PC)

被引次数

2

摘要： 合成了1,10-菲哆啉-1-氧化物(PhenNO)的稀土配合物RE2(PhenNO)6(Ac)2(ClO4)4·3H2O(RE=Eu,Gd,Tb,Ho,Er,Yb;Ac=乙酸根),经元素分析确定了配合物的组成,探讨了配合物的组成和结构对荧光性质的影响.

关键词: 1, 10-菲啰啉-1-氧化物, 乙酸, 稀土, 双核配合物

Abstract: The binuclear complexes,hexa(1,10-phenanthroline-N-oxide)-bis(μ-acetato-O,O') bis (rare earth (Ⅲ)) perchlorate trihydrate(where,rare earth=Eu,Gd,Tb,Ho,Er,Yb),were synthesized and characterized by elementary analysis,molecular weights,molar conductances,IRspectra,electronic spectra,fluorescence spectra,TG and DSC measurements.

Key words: 1,10-Phenanthroline-N-oxide, Acetic acid, Rare earth, Binuclear complexes

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