高等学校化学学报

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (12): 1582.

• 论文 • 上一篇    下一篇

簇合物[Fe(DMF)6][W2S6]的合成、结构和性能研究

张致贵1, 王涛1, 牛淑云1, 董卫彤1, 樊玉国2   

  1. 1. 吉林大学化学系, 长春, 130023;
    2. 吉林大学理论化学研究所
  • 收稿日期:1991-12-19 修回日期:1992-10-14 出版日期:1992-12-24 发布日期:1992-12-24
  • 通讯作者: 张致贵

Studies on the Synthesis, Structure and Properties of Cluster [Fe(DMF)6][W2S6]

ZHANG Zhi-Gui1, WANG Tao1, NIU Shu-Yun1, DONG Wei-Tong1, FAN Yu-Guo2   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023;
    2. Institute of Theoretical Chemistry, Jilin University, Changchun
  • Received:1991-12-19 Revised:1992-10-14 Online:1992-12-24 Published:1992-12-24

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摘要： 以(NH4)2WS4、FeCl3和NaS2CNC5H10为原料,合成出[Fe(DMF)6][W2S6]簇合物,用X射线衍射法测定了晶胞结构.其晶胞参数为a=0.8778(1)nm,b=0.9467(3)nm,c=1.1362(6)nm,α=71.506(1)°,β=74.775(2)°,γ=74.775(2)°,ν=0.84806nm3,Z=1.晶体结构经块矩阵最小二乘法精修后,最终偏离因子R=0.0811.此外还进行了红外光谱、紫外可见光谱的测定.

关键词: 簇合物, [Fe(DMF)6][W2S6], 结构与性能

Abstract: A novel cluster [Fe(DMF)6][W2S6] was prepared by using(NH4)2WS4,FeCl3 and NaS2CNC5H10 as the reaction materials.Its structure was determined by X-ray method.The parameters of the crystal cell for the compound are a=0.8778(1)nm,b=0.9467(3)nm,c=l.1362(6)nm,α=71.506(1)°o,β=74.775(2)°,γ=74.775(2)°,V=0.84806 nm3 and Z=1.The structure was refined by block-diagonal matrix least square method,and the final agreement factor is R=0.0811.Moreover,the infrared spectra and UV-Visible spectra were measured.

Key words: Cluster, [Fe(DMF)6][W2S6], Structure and properties

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