高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (12): 1586.

• 论文 • 上一篇    下一篇

快离子导体在甲烷氧化偶联反应中的作用

毕颖丽1, 李力涛1, 甄开吉1, 杨向光1, 魏诠2, 李森梓2   

  1. 1. 吉林大学化学系, 长春, 130023;
    2. 吉林大学分析测试中心
  • 收稿日期:1992-01-18 修回日期:1992-06-15 出版日期:1992-12-24 发布日期:1992-12-24
  • 通讯作者: 毕颖丽
  • 基金资助:

    国家自然科学基金

Catalytical Behaviour of Superionic Conductors in Oxidative Coupling of Methane

BI Ying-Li1, LI Li-Tao1, ZHEN Kai-Ji1, YANG Xiang-Guang1, WEI Quan2, LI Sen-Zi2   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023;
    2. Analytical and Testing Center, Jilin University, Changchun
  • Received:1992-01-18 Revised:1992-06-15 Online:1992-12-24 Published:1992-12-24

摘要: 本文分别以离子型导体La2O3和CaO载体,添加A2BO4型快离子导体,发现催化剂的C2烃收率与添加的快离子导体迁移能力有很好的顺变关系。

关键词: 甲烷, 氧化偶联, 快离子导体

Abstract: The essence and common nature of the oxidation-coupling of methane are studied and explored.In order to increase C2 yield,the superionic conductors as the catalysts were added into the ionic conductors CaOand La2O3 for enhancing the charge transfer in the reaction.It is found that the type of charge transfer strongly influences the properties of the catalysts in the above reaction and C2 yield is coincident with the charge transfer ability of the added superionic conductors.

Key words: Methane, Oxidation coupling, Superionic conductor

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