高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (2): 165.

• 论文 • 上一篇    下一篇

镉与2-[(邻羟苄叉)氨基]酚和吡啶配合物的表征和晶体结构

刘德信, 崔学桂, 郝树萱, 李凤玲   

  1. 山东大学应用化学系, 250100
  • 收稿日期:1989-07-26 出版日期:1991-02-24 发布日期:1991-02-24
  • 通讯作者: 刘德信

Characterization and Structure of Complex of Cadmium with 2-[(o-Hydroxybenzylidene)amino]phenol and Pyridine

Liu De-xin, Cui Xue-gui, Hao Shu-xuan, Li Feng-ling   

  1. Department of Applied Chemistry, Shandong University, Jinan, 250100
  • Received:1989-07-26 Online:1991-02-24 Published:1991-02-24

PDF (PC)

被引次数

6

摘要： 合成了镉与2-[(邻羟苄叉)氨基]酚(H2Sap)和吡啶配合物,Cd2(C13H9No2)2(C5H5N)6.测定其晶体属单针晶系,P21/c空间群,a=14. 006(3)Å, b=10. 362(1)Å, c=18. 435(2)Å,β=111.29(1)°,V=2492. 77Å3M=1121.86, Z=2, DI=1.495g/cm3, μ=9. 023 cm-1, F(000)=1136的配位构型为八面体.用红外、核磁、热分析等枝术进行了表征.

关键词: 镉, 配合物, 性质, 结构

Abstract: Acomplex of cadmium with 2-[(o-hydroxybenzylidene) amino] phenol (H2Sap) and pyri-dine Cd2(C13H9NO2)2(C5H5)6was prepared. Its structure was determined. It is found that the crystal belongs to the monoclinic system with space group P21/c, and the unit cell parameters are:a=14. 006(3)Å, b=10. 362(1)Å, c=18. 435(2)Å,β=111.29(1)°,V=2492. 77Å3M=1121.86, Z=2, DI=1.495g/cm3, μ=9. 023 cm-1, F(000)=1136.The cadmium coordination configuration is octahedral. The properties of the complex have been characterized by IR, NMR, DTA and TGtechniques.

Key words: Cadmium, Coordination compound, Properties, Structure

TrendMD: