高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (2): 157.

• 论文 • 上一篇    下一篇

二[4,4,4-三氟-1-(2-噻吩基)丁二酮-1,3]合铜-二喹啉配合物的合成和晶体结构

俞运鹏1, 朱多林1, 徐正2, 苟少华2, 游效曾2, 刘世雄3, 林墀昌3   

  1. 1. 镇江师范专科学校化学系, 212003;
    2. 南京大学配位化学研究所;
    3. 福州大学结构化学研究所
  • 收稿日期:1989-04-24 出版日期:1991-02-24 发布日期:1991-02-24
  • 通讯作者: 俞运鹏
  • 基金资助:

    国家自然科学基金

Synthesis and Crystal Structure of the Complex of Bis[4,4,4-Trifluoro-1-(2-Thienyl) Butanedione-1,3] Copper(Ⅱ) with Diquinoline

Yu Yun-peng1, Zhu Duo-lin1, Xu Zheng2, Gou Shao-hua2, You Xiao-zeng2, Liu Shi-xiong3, Lin Chi-chang3   

  1. 1. Department of Chemistry, Zhenjiang Teachers' College, Zhenjiang, 212003;
    2. Coordination Chemistry Institute, Nanjing University, Nanjing;
    3. Institute of Structural Chemistry, Fuzhou Universisty, Fuzhou
  • Received:1989-04-24 Online:1991-02-24 Published:1991-02-24

PDF (PC)

被引次数

1

摘要： 用X射线衍射法测定标题化合物的晶体结构.晶体空间群为P1,a=9. 782(2) Å,6=9. 978(2)Å, c=9. 562(2)Å, α=91.62(2)°, β=111. 09(1)°, γ=104. 75(2)°,V=834. 7A3,Z=1,Dc=1. 52 g·cm-3Cu(Ⅱ)与2个4,4,4-三氟-1-(2-噻吩基)丁二酮-1,3中的4个氧原子组成正方形,在正方形的轴向上。2个喹啉分子的氮原子与Cu(Ⅱ)配位,形成了六配位的八面体配合物.研究了配合物的热谱、红外光谱.

关键词: 4, 4, 4-三氟-1-(2-噻吩基)丁二酮-1, 3, 喹啉, 铜配合物, 晶体结构

Abstract: The title compound was synthesized and characterized by elemental analysis, thermo-analy-sis(TG-DTA), 1R and X-ray diffraction analysis.The carystal belongs to triclinic system with a=9. 782(2)Å,6=9. 978(2)Å, c=9. 562(2)Å, α=91.62(2)°, β=111. 09(1)°, γ=104. 75(2)°,V=834. 7A3,Z=1,Dc=1. 52 g·cm-3,Dm=1.51 g·cm-3,M=764. 22, F(000)=387e and the space group is P1.The structure was solved by patterson method and refined by least squares method to final R=0. 045 for 2491 reflections. Cu (Ⅱ) is hexacoordinated and lies on the plane formed by four oxygen atoms, two quinoline molecules with Cu(Ⅱ) form the trans-bis-quinoline addut. The plane CuO4is almost perpendicular to the quinoline ring, the angle between the planes is 93. 8°.

Key words: 4,4,4-Trifluoro-1-(2-thienyl) butanedione-1,3,Quinoline, Copper complex, Crystal structure

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