高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (3): 250.

• 研究论文 • 上一篇    下一篇

单纯形-偏差图形识别法在极谱吸附波研究中的应用

张正奇, 俞汝勤   

  1. 湖南大学化学化工系
  • 收稿日期:1988-09-17 出版日期:1990-03-24 发布日期:1990-03-24
  • 通讯作者: 张正奇

Application of Simplex-Deviation-Pattern Recognition to Studies of Adsorptive Polarographic Wave

Zhang Zhengqi, Yu Ruqin   

  1. Department of Chemistry and Chemical Engineering, Hunan University, Changsha
  • Received:1988-09-17 Online:1990-03-24 Published:1990-03-24

PDF (PC)

被引次数

15

摘要： 本文提出了单纯形-偏差图形识别法,并用此方法确定了2-QADNm和2,7-TADN在汞电极上的吸附服从Frumkin吸附等温线,测定了有关参数。

关键词: 单纯形法, 偏差图形识别, 2-QADNm, 2, 7-TADN

Abstract: In this paper the simplex-deviation-pattern recognition is proposed and applied to the studies of adsorptive polarographic wave. With simplex-deviation-pattern recognition it is estimated that the adsorption of 2-QADNm and 2,7-TADNobeys Frumkin isotherm. The values of adsorption coefficient, interaction coefficient between adsorbant molecules and adsorption free energy were determined.

Key words: Simplex, Deviation-pattern recognition, 2-QADNm,2,7-TADN

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