高等学校化学学报

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固态发光碳点的机理与合成、应用的研究进展

潘卓涵,艾琳,卢思宇   

  1. 郑州大学化学学院
  • 收稿日期:2025-03-24 修回日期:2025-04-15 网络首发:2025-04-16 发布日期:2025-04-16
  • 通讯作者: 卢思宇 E-mail:sylu2013@zzu.edu.cn
  • 基金资助:
    河南省优秀青年科学基金(批准号:252300421167), 河南省科技计划联合基金优势学科培育联合基金培育项目(批准号:242301420045),国家自然科学基金青年基金(批准号:52103239)及国家自然科学基金(批准号:U24A2079)资助

Research progress on the mechanism, synthesis and application of solid-state luminescent carbon dots

PAN Zhuohan, AI Lin, LU Siyu   

  1. College of Chemistry, Zhengzhou University
  • Received:2025-03-24 Revised:2025-04-15 Online First:2025-04-16 Published:2025-04-16
  • Contact: LU Siyu E-mail:sylu2013@zzu.edu.cn
  • Supported by:
    Supported by the Natural Science Foundation of Henan, China(No.25300421167), the Science and Technology Plan Joint Fund of Henan, China(No.242301420045), the National Natural Science Foundation of China Youth Fund(No.52103239), the National Natural Science Foundation of China(No.U24A2079)

摘要: 碳点(CDs)作为一种光学性能优异的零维碳纳米材料在光电器件、生物成像等领域得到了广泛的应用。然而固态CDs由于聚集造成的共振能量转移与π-π堆积将会导致固态发光猝灭,极大阻碍了其作为荧光粉或固态照明等发面应用。因此,研究人员探究了多种获得固态发光CDs的方式,本文回顾了CDs固态发光的机理、现阶段的常用的合成策略,介绍了固态发光CDs最新的应用领域。最后提出了制备固态发光CDs现阶段的难题以及未来需要面临的挑战。

关键词: 碳点, 固态发光, 荧光, 余辉

Abstract: As a 0-dimensional carbon nanomaterial with excellent optical properties, carbon dots (CDs) has been widely used in optoelectronic devices, biological imaging and other fields. However, due to the resonance energy transfer and π-π accumulation caused by the aggregation of solid CDs, the solid emission quenching has greatly hindered its application as phosphors. So the researchers explored a variety of ways to obtain solid-state luminescent CDs. In this paper, the mechanism, classification and research progress of solid-state luminescence CDs are reviewed, and the latest application fields of solid-state luminescence CDs are introduced. Finally, the difficulties and future challenges in the preparation of solid-state luminescent CDs are presented.

Key words: Carbon dots, Solid state luminescence, Fluorescence, Afterglow

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